From Li clusters to nanocatalysis: a brief tour of 40 years of cluster chemistry

2021 ◽  
pp. 120680
Author(s):  
Gianfranco Pacchioni
Keyword(s):  
Cluster Chemistry

Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion

2005 ◽  
Vol 70 (4) ◽  
pp. 430-440 ◽  
Author(s):  
Michael J. Carr ◽  
Michael G. S. Londesborough ◽  
Jonathan Bould ◽  
Ivana Císařová ◽  
Bohumil Štíbr ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Sodium Hydride ◽  
Hydrogen Atoms ◽  
Subsequent Reaction ◽  
Cluster Chemistry ◽  
Cluster Shape ◽  
Open Face

The deprotonation of S2B17H17 with sodium hydride and subsequent reaction with [PtCl2(PMe2Ph)2] gives the new macropolyhedral metallathiaborane [(PMe2Ph)2PtS2B16H16], of which the cluster consists of a conventional eleven-vertex nido {SB10} unit, fused, with two boron atoms in common, with a {PtSB8} unit of unique ten-vertex neo-arachno constitution and geometry. The latter geometry suggests a configuration for the previously structurally uncharacterised [B10H15]- anion; starting from this configuration, DFT calculations of structure and thence of boron nuclear shieldings, which are found very closely to mimic those found experimentally, thence support a fluxional structure for [B10H15]- with three {BHB(bridging)} and two {BH(endo)} hydrogen atoms around a six-membered open face.

The heteronuclear cluster chemistry of the Group IB metals

1988 ◽  
Vol 344 (3) ◽  
pp. 411-417 ◽  
Author(s):  
Paul J. McCarthy ◽  
Ian D. Salter ◽  
Vladimir Šik
Keyword(s):  
Cluster Chemistry ◽  
Heteronuclear Cluster

Cluster chemistry

1994 ◽  
Vol 469 (1) ◽  
pp. 89-97 ◽  
Author(s):  
Michael I. Bruce ◽  
Jonathan R. Hinchliffe ◽  
Richard Surynt ◽  
Brian W. Skelton ◽  
Allan H. White
Keyword(s):  
Cluster Chemistry

Theoretical aspects of metal cluster chemistry

1991 ◽  
Vol 63 (6) ◽  
pp. 807-812 ◽  
Author(s):  
D. M. P. Mingos
Keyword(s):  
Metal Cluster ◽  
Cluster Chemistry

Di-2-pyridyl ketone oxime in 3d-metal carboxylate cluster chemistry: a new family of mixed-valence Mn2IIMn2III complexes

2003 ◽  
Vol 6 (8) ◽  
pp. 1056-1060 ◽  
Author(s):  
Constantinos J Milios ◽  
Catherine P Raptopoulou ◽  
Aris Terzis ◽  
Ramon Vicente ◽  
Albert Escuer ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Metal Carboxylate ◽  
Cluster Chemistry ◽  
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