Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes

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Hans-Joachim Drexler ◽  
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Lei Sun ◽  
Qinggang Liu ◽  
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A Schiff base-modified silver catalyst was developed for the direct carboxylation of terminal alkynes with CO2, enabling the efficient synthesis of valuable alkynyl carboxylic acids.


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