A series of diamidophosphite ligands of various structure and denticity were synthesized from (11S,12S)-bis(hydroxymethyl)-9,10-dihydro-9,10-ethanoanthracene as a “roof shape” 1,4-diol. On the basis of these ligands, we obtained three types of...
We report the synthesis, characterisation, and catalytic application of a palladium (II) complex [(4-{1,2-C6H4(N=CH-C6H4O)2}Pd] (1) supported by a dianionic salen ligand [1,2-C6H4(N=CH-C6H4O)2]2- (L) as a molecular pre-catalyst for the hydroboration...
As the bridge between single metal atoms and metal nanoclusters, atomically precise metal complexes are of great significance for the controlled synthesis and catalytic applications at the atomic level. Herein,...