Polarographic determination of sulfur dioxide in mercury(II)-sulfur dioxide complex

1967 ◽  
Vol 39 (2) ◽  
pp. 260-261 ◽  
Author(s):  
Leonard L. Ciaccio ◽  
Thano P. Cotsis



1917 ◽  
Vol 9 (12) ◽  
pp. 1148-1148
Author(s):  
James Withrow
Keyword(s):  


1986 ◽  
Vol 51 (10) ◽  
pp. 2077-2082 ◽  
Author(s):  
Jan Langmaier ◽  
František Opekar

Gold porous membrane electrode has been used for the potentiometric determination of small amounts of sulfur dioxide absorbed in the solutions of sodium tetrachloromercurate or sodium hydroxide. Sulfur dioxide is released by the reaction with an acid into a stream of nitrogen and led to the electrode immersed into the solution of iodine monochloride. Part of SO2 penetrates through the membrane pores into the solution where it is oxidized. The electrode redox potential change is a measure of the SO2 concentration in the absorption solution. In the solution of 1 . 10-5 M[ICl2]- in 0.02 M-HClO4 the limit of quantitation was found to be 0.07 ng SO2 . ml-1. The relative standard deviations of 1.4% and 2.5% were found for the determinations of 10 ng and 0.5 ng of SO2, respectively. Higher concentrations of H2S interfere only in the hydroxide solution. About 10 samples can be analyzed per one hour.



1987 ◽  
Vol 52 (3) ◽  
pp. 609-615
Author(s):  
A. Díaz ◽  
S. González ◽  
A. Arévalo

The minimum on the polarographic curves for Bi(III) reduction in HCl solutions occurring when small amounts of surfactants are present can be used for their quantitative determination. The form of the polarograms was examined with respect to the concentration of the surfactant, and the range of concentrations in which the method of determination can be used is discussed.



1959 ◽  
Vol 31 (7) ◽  
pp. 1217-1219 ◽  
Author(s):  
R. E. Van Atta ◽  
D. R. Jamieson




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