Kinetics and mechanism of oxidative addition reactions. I. Reactions of methyl iodide and ethyl iodide with .pi.-cyclopentadienylcarbonylphosphine complexes of cobalt, rhodium, and iridium

1970 ◽  
Vol 9 (12) ◽  
pp. 2658-2663 ◽  
Author(s):  
William A. G. Graham ◽  
A. J. Hart-Davis
Keyword(s):  
Methyl Iodide ◽  
Oxidative Addition ◽  
Kinetics And Mechanism ◽  
Ethyl Iodide ◽  
Addition Reactions

Reactivity comparison of five-and six-membered cyclometalated platinum(ii) complexes in oxidative addition reactions

RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 85111-85121 ◽  
Author(s):  
Fatemeh Raoof ◽  
Maryam Boostanizadeh ◽  
Ahmad R. Esmaeilbeig ◽  
S. Masoud Nabavizadeh ◽  
Reza Babadi Aghakhanpour ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Ring Size ◽  
Cyclometalated Complex

A six-membered cyclometalated complex [PtMe(bzpy)(PPh3)] (bzpy = 2-benzylpyridinate) undergoes oxidative addition with methyl iodide to give [PtMe2I(bzpy)(PPh3)]. The ring size of the chelating unit has a significant impact on the rate of the reaction.

Sign in / Sign up

Export Citation Format

Share Document