Reactivity comparison of five-and six-membered cyclometalated platinum(ii) complexes in oxidative addition reactions

RSC Advances ◽  
2015 ◽  
Vol 5 (103) ◽  
pp. 85111-85121 ◽  
Author(s):  
Fatemeh Raoof ◽  
Maryam Boostanizadeh ◽  
Ahmad R. Esmaeilbeig ◽  
S. Masoud Nabavizadeh ◽  
Reza Babadi Aghakhanpour ◽  
...  
Keyword(s):  
Methyl Iodide ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Ring Size ◽  
Cyclometalated Complex

A six-membered cyclometalated complex [PtMe(bzpy)(PPh3)] (bzpy = 2-benzylpyridinate) undergoes oxidative addition with methyl iodide to give [PtMe2I(bzpy)(PPh3)]. The ring size of the chelating unit has a significant impact on the rate of the reaction.

Oxidative addition reactions of an iridium(I) complex containing phosphine-NHC

Polyhedron ◽  
2021 ◽  
Vol 198 ◽  
pp. 115083
Author(s):  
Aziza Ahmida ◽  
Fatin M. Elmagbari ◽  
Hans Egold ◽  
Gerald Henkel
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions

Reactions of the Ni(0) Compound Ni(PPh3)4 with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates

2018 ◽  
Vol 37 (15) ◽  
pp. 2450-2467 ◽  
Author(s):  
Ryley Kehoe ◽  
Markshun Mahadevan ◽  
Adeela Manzoor ◽  
Gillian McMurray ◽  
Patrick Wienefeld ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides ◽  
Addition Reactions ◽  
Radical Processes
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