Structural studies on polynuclear osmium carbonyl hydrides.  2.  Direct location of the .mu.2-hydride ligand and characterization of the 1,3-dipolar :C-HCH2P+Me2Ph ligand in the .mu.-hydrido-decacarbonyl(dimethylphenylphosphine)-.mu.-vinyl-triosmium molecule

Melvyn Rowen. Churchill; Barry G. DeBoer

doi:10.1021/ic50171a033

Structural studies on polynuclear osmium carbonyl hydrides. 2. Direct location of the .mu.2-hydride ligand and characterization of the 1,3-dipolar :C-HCH2P+Me2Ph ligand in the .mu.-hydrido-decacarbonyl(dimethylphenylphosphine)-.mu.-vinyl-triosmium molecule

Inorganic Chemistry ◽

10.1021/ic50171a033 ◽

1977 ◽

Vol 16 (5) ◽

pp. 1141-1146 ◽

Cited By ~ 37

Author(s):

Melvyn Rowen. Churchill ◽

Barry G. DeBoer

Keyword(s):

Structural Studies ◽

Hydride Ligand ◽

Osmium Carbonyl ◽

Direct Location

ChemInform Abstract: Structural Studies on Polynuclear Osmium Carbonyl Hydrides. Part 2. Direct Location of the μ2-Hydride Ligand and Characterization of the l,3-Dipolar >C-HCH2P+Me2Ph Ligand in the HOs3(CO)10(CHCH2PMe′Ph) Molecule.

Chemischer Informationsdienst ◽

10.1002/chin.197730313 ◽

1977 ◽

Vol 8 (30) ◽

pp. no-no

Author(s):

M. R. CHURCHILL ◽

B. G. DEBOER

Keyword(s):

Structural Studies ◽

Hydride Ligand ◽

Osmium Carbonyl ◽

Direct Location

ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 12. MOLECULAR GEOMETRY OF μ-CHLORO-μ-HYDRIDO-DECACARBONYLTRIOSMIUM, (μ-H)(μ-CL)OS3(CO)10, AND CHARACTERIZATION OF THE OS(μ-H)(μ-CL)OS BRIDGE

Chemischer Informationsdienst ◽

10.1002/chin.197942097 ◽

1979 ◽

Vol 10 (42) ◽

Author(s):

M. R. CHURCHILL ◽

R. A. LASHEWYCZ

Keyword(s):

Molecular Geometry ◽

Structural Studies ◽

Osmium Carbonyl

ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 3. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF DECACARBONYLDIHYDRO(TRIPHENYLPHOSPHINE)TRIOSMIUM INCLUDING DIRECT LOCATION OF BOTH TERMINAL AND μ2-BRIDGING HYDRIDE LIGANDS

Chemischer Informationsdienst ◽

10.1002/chin.197749097 ◽

1977 ◽

Vol 8 (49) ◽

Author(s):

M. R. CHURCHILL ◽

B. G. DEBOER

Keyword(s):

Crystal Structure ◽

Molecular Geometry ◽

Structural Studies ◽

Osmium Carbonyl ◽

Direct Location ◽

Hydride Ligands

Structural studies on polynuclear osmium carbonyl hydrides. 14. X-ray diffraction study of (.mu.-H)4Os4(CO)11(CNMe), including the direct location of all four bridging hydride ligands

Inorganic Chemistry ◽

10.1021/ic50204a006 ◽

1980 ◽

Vol 19 (2) ◽

pp. 306-310 ◽

Cited By ~ 11

Author(s):

Melvyn Rowen Churchill ◽

Frederick J. Hollander

Keyword(s):

Diffraction Study ◽

Structural Studies ◽

X Ray Diffraction ◽

X Ray ◽

Osmium Carbonyl ◽

Direct Location ◽

Hydride Ligands

ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 10. MOLECULAR GEOMETRY AND COMMENTS ON THE LOCATION OF THE μ2-HYDRIDE LIGAND IN (μ-H)OS3W(CO)12(η5-C5H5)

Chemischer Informationsdienst ◽

10.1002/chin.197925065 ◽

1979 ◽

Vol 10 (25) ◽

Author(s):

M. R. CHURCHILL ◽

F. J. HOLLANDER

Keyword(s):

Molecular Geometry ◽

Structural Studies ◽

Hydride Ligand ◽

Osmium Carbonyl

Structural studies on polynuclear osmium carbonyl hydrides. 1. Crystal structures of the isomorphous species undecacarbonyldihydrotriosmium and dodecacarbonyltriosmium. Role of an equatorial .mu.2-bridging hydride ligand in perturbing the arrangement of carbonyl ligands in a triangular cluster

Inorganic Chemistry ◽

10.1021/ic50170a032 ◽

1977 ◽

Vol 16 (4) ◽

pp. 878-884 ◽

Cited By ~ 269

Author(s):

Melvyn Rowen. Churchill ◽

Barry G. DeBoer

Keyword(s):

Crystal Structures ◽

Structural Studies ◽

Carbonyl Ligands ◽

Hydride Ligand ◽

Osmium Carbonyl

Structural studies on polynuclear osmium carbonyl hydrides. 12. Molecular geometry of .mu.-chloro-.mu.-hydrido-decacarbonyltriosmium, (.mu.-H)(.mu.-Cl)Os3(CO)10, and characterization of the Os(.mu.-H)(.mu.-Cl)Os bridge

Inorganic Chemistry ◽

10.1021/ic50197a041 ◽

1979 ◽

Vol 18 (7) ◽

pp. 1926-1930 ◽

Cited By ~ 31

Author(s):

Melvyn Rowen Churchill ◽

Romana A. Lashewycz

Keyword(s):

Molecular Geometry ◽

Structural Studies ◽

Osmium Carbonyl

ChemInform Abstract: STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES. 11. CRYSTAL STRUCTURE AND MOLECULAR GEOMETRY OF (μ-H)OS3(CO)10(CHCH:NET2), A SPECIES CONTAINING A μ2-HYDRIDE LIGAND AND A μ2-1,3-DIPOLAR >C-HCH:N+ET2 LIGAND

Chemischer Informationsdienst ◽

10.1002/chin.197925066 ◽

1979 ◽

Vol 10 (25) ◽

Author(s):

M. R. CHURCHILL ◽

R. A. LASHEWYCZ

Keyword(s):

Crystal Structure ◽

Molecular Geometry ◽

Structural Studies ◽

Hydride Ligand ◽

Osmium Carbonyl

Structural studies on polynuclear osmium carbonyl hydrides. 3. Crystal structure and molecular geometry of decacarbonyldihydro(triphenylphosphine)triosmium including direct location of both terminal and .mu.2-bridging hydride ligands

Inorganic Chemistry ◽

10.1021/ic50175a047 ◽

1977 ◽

Vol 16 (9) ◽

pp. 2397-2403 ◽

Cited By ~ 57

Author(s):

Melvyn Rowen. Churchill ◽

Barry G. DeBoer

Keyword(s):

Crystal Structure ◽

Molecular Geometry ◽

Structural Studies ◽

Osmium Carbonyl ◽

Direct Location ◽

Hydride Ligands

Structural studies on polynuclear osmium carbonyl hydrides. 10. Molecular geometry and comments on the location of the .mu.2-hydride ligand in (.mu.-H)Os3W(CO)12(.eta.5-C5H5)

Inorganic Chemistry ◽

10.1021/ic50193a061 ◽

1979 ◽

Vol 18 (3) ◽

pp. 843-848 ◽

Cited By ~ 14

Author(s):

Melvyn Rowen Churchill ◽

Frederick J. Hollander

Keyword(s):

Molecular Geometry ◽

Structural Studies ◽

Hydride Ligand ◽

Osmium Carbonyl