Mechanism of resolution enhancement for the electron spin echo detected electron spin resonance spectrum of alkyl radical in .gamma.-irradiated n-hexane single crystal

1988 ◽  
Vol 92 (20) ◽  
pp. 5684-5688 ◽  
Author(s):  
Tsuneki Ichikawa ◽  
Hiroshi Yoshida
1975 ◽  
Vol 30 (6-7) ◽  
pp. 750-753
Author(s):  
F. Köksal ◽  
H. Yüksel

Abstract Potassium hydrogen sulphate single crystal has been γ-irradiated at room temperature and its electron spin resonance spectrum recorded by changing the H0 static magnetic field, around an orthogonal axes system. The electron spin resonance spectrum is a single line with a slightly anisotropic g factor. The paramagnetic species has been identified as SO3- and the principal values of the g tensor has been determined as g1=g2=2.0060, g3 = 2.0045. Direction cosines of the principalvalues of the g tensor with respect to the chosen axes have been determined. The spin-orbit contribution to the g-factor has been explained.


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