Alkoxy-Substituted Titanium(IV) Chlorides as Lewis Acid Activators for Living Cationic Polymerization of Isobutyl Vinyl Ether: Control of Lewis Acidity in the Design of Initiating Systems

1995 ◽  
Vol 28 (16) ◽  
pp. 5671-5675 ◽  
Author(s):  
Masami Kamigaito ◽  
Mitsuo Sawamoto ◽  
Toshinobu Higashimura
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Lewis Acidity ◽  
Living Cationic Polymerization

Living cationic polymerization of isobutyl vinyl ether by RCOOH/Lewis acid initiating systems: effects of carboxylate ions and Lewis acid activators

1991 ◽  
Vol 24 (14) ◽  
pp. 3988-3992 ◽  
Author(s):  
Masami Kamigaito ◽  
Mitsuo Sawamoto ◽  
Toshinobu Higashimura
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization

Living cationic polymerization of isobutyl vinyl ether by hydrogen chloride/Lewis acid initiating systems in the presence of salts: in-situ direct NMR analysis of the growing species

1993 ◽  
Vol 26 (7) ◽  
pp. 1643-1649 ◽  
Author(s):  
Masami Kamigaito ◽  
Yoshihiro Maeda ◽  
Mitsuo Sawamoto ◽  
Toshinobu Higashimura
Keyword(s):  
Hydrogen Chloride ◽  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Nmr Analysis ◽  
Living Cationic Polymerization

Lewis acid-specific polymerization behaviors in living cationic polymerization of vinyl ether with a malonate group

2012 ◽  
Vol 50 (15) ◽  
pp. 2993-2998 ◽  
Author(s):  
Yukari Oda ◽  
Tomohiro Tsujino ◽  
Shokyoku Kanaoka ◽  
Sadahito Aoshima
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization

scholarly journals A well-defined block copolymer synthesis via living cationic polymerization and nitroxide-mediated polymerization using carboxylic acid-based alkoxyamines as a dual initiator

2016 ◽  
Vol 7 (8) ◽  
pp. 1659-1667 ◽  
Author(s):  
Dao Le ◽  
Trang N. T. Phan ◽  
Laurent Autissier ◽  
Laurence Charles ◽  
Didier Gigmes
Keyword(s):  
Carboxylic Acid ◽  
Block Copolymer ◽  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization ◽  
Nitroxide Mediated Polymerization ◽  
Protonic Acids

A series of carboxylic acid-based alkoxyamines associated with SnBr4, a Lewis acid, have been used as protonic acids of a binary initiating system to control the cationic polymerization of vinyl ether.

scholarly journals Living Cationic Polymerization of Vinyl Ether with a Lewis Acid/Acetylacetone Initiating System—The Role of Acetylacetone as a Protogen and a Ligand

2011 ◽  
Vol 68 (5) ◽  
pp. 349-351 ◽  
Author(s):  
Shokyoku KANAOKA ◽  
Shinya NAKAYAMA ◽  
Sadahito AOSHIMA
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization

Living cationic polymerization of isobutyl vinyl ether by trimethylsilyl iodide: Lewis acid systems on the presence of acetone: initiation via a silyloxycarbocation

1990 ◽  
Vol 23 (23) ◽  
pp. 4896-4901 ◽  
Author(s):  
Masami Kamigaito ◽  
Mitsuo Sawamoto ◽  
Toshinobu Higashimura
Keyword(s):  
Vinyl Ether ◽  
Lewis Acid ◽  
Cationic Polymerization ◽  
Living Cationic Polymerization ◽  
Trimethylsilyl Iodide
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