Palladium-Catalyzed Alkyne Insertion/Reduction Route to Trisubstituted Olefins

2013 ◽  
Vol 15 (17) ◽  
pp. 4362-4365 ◽  
Author(s):  
Erin R. Fruchey ◽  
Brendan M. Monks ◽  
Andrea M. Patterson ◽  
Silas P. Cook
Keyword(s):  
Trisubstituted Olefins ◽  
Palladium Catalyzed ◽  
Alkyne Insertion

ChemInform Abstract: Palladium-Catalyzed Alkyne Insertion/Reduction Route to Trisubstituted Olefins.

ChemInform ◽  
2014 ◽  
Vol 45 (5) ◽  
pp. no-no
Author(s):  
Erin R. Fruchey ◽  
Brendan M. Monks ◽  
Andrea M. Patterson ◽  
Silas P. Cook
Keyword(s):  
Trisubstituted Olefins ◽  
Palladium Catalyzed ◽  
Alkyne Insertion

Utilization of Sequential Palladium-Catalyzed Cross-Coupling Reactions in the Stereospecific Synthesis of Trisubstituted Olefins

2009 ◽  
Vol 13 (3) ◽  
pp. 598-606 ◽  
Author(s):  
Ioannis N. Houpis ◽  
Didier Shilds ◽  
Ulrike Nettekoven ◽  
Anita Schnyder ◽  
Erhart Bappert ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Construction of Polycyclic Heterocycles by an Alkyne Insertion and Direct Arylation Cascade

Synthesis ◽  
2011 ◽  
Vol 2011 (16) ◽  
pp. 2567-2578 ◽  
Author(s):  
Hiroaki Ohno ◽  
Tetsuaki Tanaka ◽  
Mio Yamamoto ◽  
Mutsumi Iuchi ◽  
Nobutaka Fujii
Keyword(s):  
Direct Arylation ◽  
Palladium Catalyzed ◽  
Alkyne Insertion

ChemInform Abstract: Palladium-Catalyzed Construction of Polycyclic Heterocycles by an Alkyne Insertion and Direct Arylation Cascade.

ChemInform ◽  
2011 ◽  
Vol 42 (52) ◽  
pp. no-no
Author(s):  
Hiroaki Ohno ◽  
Mio Yamamoto ◽  
Mutsumi Iuchi ◽  
Nobutaka Fujii ◽  
Tetsuaki Tanaka
Keyword(s):  
Direct Arylation ◽  
Palladium Catalyzed ◽  
Alkyne Insertion

scholarly journals Utilization of Sequential Palladium-Catalyzed Cross-Coupling Reactions in the Stereospecific Synthesis of Trisubstituted Olefins

2009 ◽  
Vol 13 (5) ◽  
pp. 1032-1032
Author(s):  
Ioannis N. Houpis ◽  
Didier Schils ◽  
Ulrike Nettekoven ◽  
Anita Schnyder ◽  
Erhart Bappert ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Stereospecific Synthesis ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

scholarly journals Palladium-catalyzed arylation of enoates with iodobenzene: stereoselective synthesis of trisubstituted olefins

2013 ◽  
Vol 24 (3) ◽  
pp. 500-506
Author(s):  
Talita de A. Fernandes ◽  
Boniek G. Vaz ◽  
Alcides J. M. da Silva ◽  
Pierre M. Esteves ◽  
Marcos N. Eberlin ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Asymmetric Hydrophosphination of Internal Alkynes: Highly Regio- and Stereoselective Construction of Axially Chiral Phosphines

2021 ◽  
Author(s):  
Danqing Ji ◽  
Jierui Jing ◽  
Yi Wang ◽  
Zisong Qi ◽  
Fen Wang ◽  
...  
Keyword(s):  
Axial Chirality ◽  
Axially Chiral ◽  
Internal Alkynes ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed ◽  
Chiral Phosphines ◽  
Kinetic Transformation ◽  
Secondary Phosphines

Palladium-catalyzed unprecedented atroposelective hydrophosphination of internal alkynes has been realized using diarylphosphines, affording C-N axially chiral trisubstituted olefins (vinylphosphines) in excellent regioselectiviry, (E)-selectivity, and enantioselectivity. The axial chirality was established via integration of hydrophosphination and dynamic kinetic transformation of the alkynes, with both symmetrical and nonsymmetrical secondary phosphines being applicable. In the latter case, additional P-central chirality has been constructed in good diastereoselectivity.

Development of a palladium catalyzed addition of boronic acids to alkynyl esters: synthesis of trisubstituted olefins as single isomers

Tetrahedron ◽  
2009 ◽  
Vol 65 (41) ◽  
pp. 8502-8506 ◽  
Author(s):  
Alexander Graham Bush ◽  
Jojo Liu Jiang ◽  
Philippa R. Payne ◽  
William W. Ogilvie
Keyword(s):  
Boronic Acids ◽  
Trisubstituted Olefins ◽  
Palladium Catalyzed

Palladium-Catalyzed Spirocyclization through C−H Activation and Regioselective Alkyne Insertion

2017 ◽  
Vol 56 (36) ◽  
pp. 10920-10923 ◽  
Author(s):  
Hyung Yoon ◽  
Martin Rölz ◽  
Felicitas Landau ◽  
Mark Lautens
Keyword(s):  
Palladium Catalyzed ◽  
Alkyne Insertion
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