Reactions of acetylenes with noble-metal carbonyl halides. 12. Synthesis, reactivity, and solution structures by multinuclear NMR studies of .sigma.-alkenylplatinum(II) complexes. X-ray structure analysis of [cyclic][Pt{C(C6H5):C(H)C(:O)Me}(CO)Cl] and [Pt{C(C6H5):C(H)C(:NC6H5)Me}(PPh3)2Cl]

1990 ◽  
Vol 9 (5) ◽  
pp. 1383-1391 ◽  
Author(s):  
Claudio Allevi ◽  
Luigi Garlaschelli ◽  
Maria Carlotta Malatesta ◽  
Fabio Ganazzoli
Keyword(s):  
Structure Analysis ◽  
Noble Metal ◽  
Metal Carbonyl ◽  
Nmr Studies ◽  
X Ray ◽  
Solution Structures ◽  
Multinuclear Nmr

Reactions of acetylenes with noble-metal carbonyl halides. Part 6. Carbonyl insertion to give cyclic organo-carbene complexes of platinum(II): synthesis and X-ray structure of the complex cis-[Pt{CC(CO2Et)C(Ph)C(CO2Et)C(Ph)O}(PPh3)Cl2]

1983 ◽  
pp. 827-833 ◽  
Author(s):  
Franco Canziani ◽  
Franco Galimberti ◽  
Luigi Garlaschelli ◽  
Maria Carlotta Malatesta ◽  
Alberto Albinati ◽  
...  
Keyword(s):  
Noble Metal ◽  
Metal Carbonyl ◽  
Carbene Complexes ◽  
X Ray

Übergangsmetall-Carben-Komplexe, CXXVI [1]. Darstellung und Struktur symmetrischer Hydroxycarben-Anhydrid-Komplexe des Mangans und Rheniums / Transition Metal Carbene Complexes, CXXVI [1]. Preparation and Structure of Symmetrica! Hydroxycarbene Anhydride Complexes of Manganese and Rhenium

1982 ◽  
Vol 37 (10) ◽  
pp. 1284-1288 ◽  
Author(s):  
Ernst Otto Fischer ◽  
Jiabi Chen ◽  
Ulrich Schubert
Keyword(s):  
Transition Metal ◽  
Structure Analysis ◽  
Metal Carbonyl ◽  
Carbene Complexes ◽  
X Ray ◽  
Carbyne Complexes ◽  
Hydrolysis Of ◽  
Controlled Hydrolysis ◽  
Symmetrical Anhydrides

Abstract Symmetrical anhydrides of hydroxycarbene complexes of manganese and rhenium, [π-C5H5(CO)2MC(R)]2O, (M = Mn, Re) are prepared by reaction of cationic carbyne complexes [π-C5H5(CO)2MCR]BX4 with the corresponding metal carbonyl acylates Li[π-C5H5(CO)2MC(O)R]. [π-C5H5(CO)2MnC(C6H5)]2O is also obtained by controlled hydrolysis of π-C5H5(CO)2MnCX(Br)Ce6H5. The new complexes are characterized spectroscopically and by an X-ray structure analysis of [π-C5H5(CO)2MnC(C6H5)2O.

Carbon–carbon coupling on tetrahedral iridium clusters: X-ray molecular structures and multinuclear NMR studies of the two isomeric forms of [Ir4(CO)6(μ3-η2-HCCPh)(μ2-η4-C4H2Ph2)(μ-PPh2)2]

2004 ◽  
Vol 689 (22) ◽  
pp. 3513-3519 ◽  
Author(s):  
Maria Helena Araujo ◽  
Maria D. Vargas ◽  
Anthony G. Avent ◽  
Dario Braga ◽  
Fabrizia Grepioni
Keyword(s):  
Molecular Structures ◽  
Nmr Studies ◽  
X Ray ◽  
Multinuclear Nmr

ChemInform Abstract: Synthesis of the First Decametal Nitrido Cluster; X-Ray Crystal Structure Analysis and 14N NMR Studies of ((Ph3P)2N)(Ru10N(CO)24)

ChemInform ◽  
2010 ◽  
Vol 23 (10) ◽  
pp. no-no
Author(s):  
P. J. BAILEY ◽  
G. C. CONOLE ◽  
B. F. G. JOHNSON ◽  
J. LEWIS ◽  
M. MCPARTLIN ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Nmr Studies ◽  
X Ray ◽  
14N Nmr

X-ray structure and multinuclear NMR studies of platinum(II) and palladium(II) complexes with 5,7-ditertbutyl-1,2,4-triazolo[1,5-a]pyrimidine

Polyhedron ◽  
2007 ◽  
Vol 26 (18) ◽  
pp. 5349-5354 ◽  
Author(s):  
Iwona Łakomska ◽  
Magdalena Barwiołek ◽  
Andrzej Wojtczak ◽  
Edward Szłyk
Keyword(s):  
Nmr Studies ◽  
X Ray ◽  
Multinuclear Nmr

ChemInform Abstract: Reactions of Acetylenes with Noble Metal Carbonyl Halides. Part 10. Synthesis and X-Ray Structural Characterization of a New Substituted Diplatina-dioxapentalene Complex Bicyclic (Cl(CO)Pt(CMe=C(COOMe)C(=O))PtCl(PPh3)).

ChemInform ◽  
1988 ◽  
Vol 19 (15) ◽  
Author(s):  
C. ALLEVI ◽  
R. DELLA PERGOLA ◽  
L. GARLASCHELLI ◽  
M. C. MALATESTA ◽  
A. ALBINATI ◽  
...  
Keyword(s):  
Noble Metal ◽  
Structural Characterization ◽  
Metal Carbonyl ◽  
X Ray

X-ray structure and multinuclear NMR studies of platinum(II) complexes with 5-methyl-1,2,4-triazolo[1,5-a]pyrimidin-7(4H)-one

Polyhedron ◽  
2007 ◽  
Vol 26 (4) ◽  
pp. 803-810 ◽  
Author(s):  
Iwona Łakomska ◽  
Andrzej Wojtczak ◽  
Jerzy Sitkowski ◽  
Lech Kozerski ◽  
Edward Szłyk
Keyword(s):  
Nmr Studies ◽  
X Ray ◽  
Multinuclear Nmr
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