Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes

2019 ◽  
Vol 48 (46) ◽  
pp. 17174-17178 ◽  
Author(s):  
Lucas A. Freeman ◽  
Jacob E. Walley ◽  
Diane A. Dickie ◽  
Robert J. Gilliard
Keyword(s):  
Magnesium Hydride ◽  
Heterocyclic Carbenes ◽  
Synthesis And Characterization ◽  
Hydride Complexes

Herein we report the synthesis and characterization of dinuclear magnesium–hydride complexes coordinated by NHCs, [(IiPrMe2)Mg(μ-H)(N(SiMe3)2)]2and {(IiPrMe2)Mg(μ-H)[((CH2)Me2Si)2N]}2(IiPrMe2= N,N’-diisopropyl-2,3-dimethylimidazol-2-ylidine).

scholarly journals Synthesis and characterization of novel olefin complexes of palladium(0) with chelating bis(N-heterocyclic carbenes) as spectator ligands

Polyhedron ◽  
2018 ◽  
Vol 154 ◽  
pp. 382-389 ◽  
Author(s):  
T. Scattolin ◽  
L. Canovese ◽  
F. Visentin ◽  
C. Santo ◽  
N. Demitri
Keyword(s):  
Heterocyclic Carbenes ◽  
Synthesis And Characterization

Reactions of [(dmpe)2MnH(C2H4)]: synthesis and characterization of manganese(i) borohydride and hydride complexes

2020 ◽  
Vol 49 (29) ◽  
pp. 9983-9994
Author(s):  
Jeffrey S. Price ◽  
Declan M. DeJordy ◽  
David J. H. Emslie ◽  
James F. Britten
Keyword(s):  
Reaction Pathways ◽  
Synthesis And Characterization ◽  
Hydride Complexes

Reactions of trans-[(dmpe)2MnH(C2H4)] with hydroboranes and phosphines afforded manganese(i) borohydride and hydride complexes; reaction pathways, structures and bonding are discussed.

Synthesis and Characterization of Silver(I), Gold(I), and Gold(III) Complexes Bearing Amino-Functionalized N-Heterocyclic Carbenes

2011 ◽  
Vol 30 (10) ◽  
pp. 2755-2764 ◽  
Author(s):  
Christoph Topf ◽  
Christa Hirtenlehner ◽  
Manfred Zabel ◽  
Manuela List ◽  
Michel Fleck ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Synthesis And Characterization

Synthesis and characterization of new pentamethylcyclopentadienyl iridium hydride complexes

2012 ◽  
Vol 715 ◽  
pp. 113-118 ◽  
Author(s):  
María Talavera ◽  
Sandra Bolaño ◽  
Jorge Bravo ◽  
Jesús Castro ◽  
Soledad García-Fontán
Keyword(s):  
Synthesis And Characterization ◽  
Hydride Complexes

Facile synthesis of air-stable heterobimetallic osmium-silver hydride complexes

2021 ◽  
Author(s):  
Haiyu Zhou ◽  
Tongtong Bai ◽  
Yanlin Pan ◽  
Yongliang Wei ◽  
Tongdao Wang
Keyword(s):  
Synthesis And Characterization ◽  
Facile Synthesis ◽  
Hydride Complexes

The synthesis and characterization of air-stable heterobimetallic Os-Ag hydrides were described. All of the new heterobimetallic Os-Ag hydrides are neutral, and the in-situ generated and presynthesized cis-[Os](H)-C≡C-R units in these...

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