Oxyallyl Cation Promoted Dearomative Semipinacol Rearrangement: Facile Stereodivergent Synthesis of Spiro-indolines with Contiguous Quaternary Centers

2021 ◽  
Author(s):  
Yu-Yang Xie ◽  
Yun-Peng Wang ◽  
Xiao-Jing Zhao ◽  
Ai-Fang Wang ◽  
Zhi-Min Chen ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Quaternary Centers ◽  
Semipinacol Rearrangement ◽  
Oxyallyl Cation

A novel oxyallyl cation promoted semipinacol rearrangement of indole-type allylic alcohols was disclosed for the stereo-divergent synthesis of spiro-indolines. A variety of spiro-indolines were obtained with moderate to good yields....

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

2013 ◽  
Vol 125 (37) ◽  
pp. 9963-9967 ◽  
Author(s):  
Zhi-Min Chen ◽  
Wei Bai ◽  
Shao-Hua Wang ◽  
Bin-Miao Yang ◽  
Yong-Qiang Tu ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Semipinacol Rearrangement

Arylation and Vinylation of Alkenes Based on Unusual Sequential Semipinacol Rearrangement/Grob Fragmentation of Allylic Alcohols

2008 ◽  
Vol 73 (19) ◽  
pp. 7797-7799 ◽  
Author(s):  
Dao-Yi Yuan ◽  
Yong-Qiang Tu ◽  
Chun-An Fan
Keyword(s):  
Allylic Alcohols ◽  
Grob Fragmentation ◽  
Semipinacol Rearrangement

Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

2019 ◽  
Vol 131 (36) ◽  
pp. 12621-12626 ◽  
Author(s):  
Yu‐Yang Xie ◽  
Zhi‐Min Chen ◽  
Hui‐Yun Luo ◽  
Hui Shao ◽  
Yong‐Qiang Tu ◽  
...  
Keyword(s):  
Lewis Base ◽  
Allylic Alcohols ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Semipinacol Rearrangement

Quinine/Selectfluor Combination Induced Asymmetric Semipinacol Rearrangement of Allylic Alcohols: An Effective and Enantioselective Approach to α-Quaternary β-Fluoro Aldehydes.

ChemInform ◽  
2006 ◽  
Vol 37 (11) ◽  
Author(s):  
Min Wang ◽  
Bao Min Wang ◽  
Lei Shi ◽  
Yong Qiang Tu ◽  
Chun-An Fan ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Semipinacol Rearrangement

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

2013 ◽  
Vol 52 (37) ◽  
pp. 9781-9785 ◽  
Author(s):  
Zhi-Min Chen ◽  
Wei Bai ◽  
Shao-Hua Wang ◽  
Bin-Miao Yang ◽  
Yong-Qiang Tu ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Semipinacol Rearrangement

Lewis-Acid-Mediated Thiocyano Semipinacol Rearrangement of Allylic Alcohols for Construction of α-Quaternary Center β-Thiocyano Carbonyls

2019 ◽  
Vol 21 (23) ◽  
pp. 9550-9554 ◽  
Author(s):  
Xu-Feng Song ◽  
Ai-Hui Ye ◽  
Yu-Yang Xie ◽  
Jia-Wei Dong ◽  
Chao Chen ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Allylic Alcohols ◽  
Quaternary Center ◽  
Semipinacol Rearrangement

Lewis Base/Brønsted Acid Co‐catalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di‐ and Trisubstituted Allylic Alcohols

2019 ◽  
Vol 58 (36) ◽  
pp. 12491-12496 ◽  
Author(s):  
Yu‐Yang Xie ◽  
Zhi‐Min Chen ◽  
Hui‐Yun Luo ◽  
Hui Shao ◽  
Yong‐Qiang Tu ◽  
...  
Keyword(s):  
Lewis Base ◽  
Allylic Alcohols ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
Semipinacol Rearrangement

ChemInform Abstract: Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols.

ChemInform ◽  
2014 ◽  
Vol 45 (7) ◽  
pp. no-no
Author(s):  
Zhi-Min Chen ◽  
Wei Bai ◽  
Shao-Hua Wang ◽  
Bin-Miao Yang ◽  
Yong-Qiang Tu ◽  
...  
Keyword(s):  
Allylic Alcohols ◽  
Semipinacol Rearrangement
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