Bimetallic systems. Part 19. Chromium(0)–, molybdenum(0)–, or tungsten(0)–iron(0) carbonyl complexes containing one or two bridging Ph2PCH2PPh2ligands: crystal structure of [(OC)3Mo(µ-Ph2PCH2PPh2)2Fe(CO)3]

1987 ◽  
pp. 1489-1493 ◽  
Author(s):  
Grant B. Jacobsen ◽  
Bernard L. Shaw ◽  
Mark Thornton-Pett
Keyword(s):  
Crystal Structure ◽  
Carbonyl Complexes ◽  
Bimetallic Systems

Crystal structure of trans-[W(CO)4(η2-C2H4)2] and IR and 1H NMR studies of the reactions of this and related ethene carbonyl complexes of tungsten(0), [W(CO)n(η2-C2H4)6- n] ( n=3–5)

1999 ◽  
Vol 23 (4) ◽  
pp. 407-416 ◽  
Author(s):  
Teresa Szymańska-Buzar ◽  
Krystyna Kern ◽  
Anthony J. Downs ◽  
Timothy M. Greene ◽  
Leigh J. Morris ◽  
...  
Keyword(s):  
Crystal Structure ◽  
1H Nmr ◽  
Carbonyl Complexes ◽  
Nmr Studies

Iron carbonyl complexes of cithiocarbonates. X-ray crystal structure of Fe4(CO)12S(SCH2C5H4FeC5H5)(SCH3)

1981 ◽  
Vol 210 (1) ◽  
pp. C1-C4 ◽  
Author(s):  
Henri Patin ◽  
Gerard Mignani ◽  
Christian Mahe ◽  
Jean-Yves Le Marouille ◽  
Alain Benoit ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Iron Carbonyl ◽  
Carbonyl Complexes ◽  
X Ray

Reaktionen koordinierter Liganden, III [1]. Stabilisierung von Dimenthyldiphosphen und Menthylphosphiniden als Brückenliganden in Metallcarbonylkomplexen / Reaction of Coordinated Ligands, III [1]. Stabilization of Dim enthyldiphosphene and Menthylphosphinidene as Bridging Ligands in Metal Carbonyl Complexes

1986 ◽  
Vol 41 (5) ◽  
pp. 629-639 ◽  
Author(s):  
Anna-Margarete Hinke ◽  
Axel Hinke ◽  
Wilhelm Kuchen ◽  
Wolfgang Hönle
Keyword(s):  
Crystal Structure ◽  
Double Bond ◽  
Complex Formation ◽  
Main Product ◽  
Metal Carbonyl ◽  
Crystal Structure Analysis ◽  
Carbonyl Complexes ◽  
Bridging Ligands ◽  
Metal Carbonyl Complexes ◽  
Chromium Compounds

Abstract Reduction of MentPBr2M(CO)5 1 (M = Cr, W) with magnesium in THF yields the diphos­phene complex (CO)5M(Ment)P=P(Ment)M(CO)5 2 as the main product. In addition, a phosphinidene complex, (CO)5M(Ment)PM(CO)5 (3) is also formed. The latter is obtained in larger amounts, if the reaction is carried out in the presence of M(CO)5THF. The proposed structures are confirmed by NMR and UV data as well as - in the case of the chromium compounds (2a, 3a) - by crystal structure analysis. Compound 2a is obtained only as the frans-isomer. The P-P distance in 2a (204.0 pm) indicates a double bond which does not participate in the complex formation. The P-Cr distance in 3a (average: 230.3 pm) is within the low est range found for this element combination. Reaction of 2a with LiAlH4 yields the diphosphane complex (CO)5CrMent(H)P-P(H)MentCr(CO)5 4 as a mixture of “meso” and “rac” diastereomers.

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