Electron paramagnetic resonance studies of metal–metal interactions in manganese(II) complexes. The 10/3 effect

1973 ◽  
Vol 69 (0) ◽  
pp. 355-362 ◽  
Author(s):  
E. Pleau ◽  
G. Kokoszka
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Paramagnetic Resonance ◽  
Metal Interactions ◽  
Metal Metal ◽  
Electron Paramagnetic

Spectral Evidence for Heterodimerization of Water-Soluble Metalloporphyrins

1998 ◽  
Vol 02 (01) ◽  
pp. 61-68 ◽  
Author(s):  
SAFİYE SAĞ ERDEM
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Ir Spectra ◽  
Water Soluble ◽  
Paramagnetic Resonance ◽  
Metal Interactions ◽  
Spectral Evidence ◽  
Metal Metal ◽  
Electron Paramagnetic

The formation of water-soluble metalloporphyrin heterodimers from Fe ( III ), Cu ( II ) and Ni ( II ) complexes of 5,10,15,20-tetrakis(4-carboxyphenyl) porphyrin and 5,10,15,20-tetrakis(4-N-methylpyridyl)porphyrin has been investigated using UV-vis, IR and electron paramagnetic resonance spectra. Absorption and IR spectra confirmed the formation of dimers and electron paramagnetic resonance spectra showed evidence for the metal-metal interactions in the dimers.

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