61Ni MÖSSBAUER EFFECT STUDIES OF THE FERRIMAGNETIC SPINEL NiCr2O4 IN AN APPLIED MAGNETIC FIELD

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-185-C1-186 ◽  
Author(s):  
P. Gütlich ◽  
H. Rummel ◽  
H. Spiering
1975 ◽  
Vol 28 (2) ◽  
pp. K143-K145 ◽  
Author(s):  
J. Piekoszewski ◽  
J. Suwalski ◽  
L. Dąbrowski ◽  
S. Makolągwa

1975 ◽  
Vol 40 (309) ◽  
pp. 89-96 ◽  
Author(s):  
C. S. Hogg ◽  
P. J. Malden ◽  
R. E. Meads

SummaryTwo clay samples originating in the kaolinized granite area near St. Austell, Cornwall, have been examined by Mössbauer spectroscopy. The iron-containing impurity in the sample with a red discoloration (sample A) has, by measurement of the hyperfine magnetic field, been identified as hematite. In the case of sample B, which was yellow in colour, preliminary Mössbauer work indicated β-FeOOH as the impurity, but detailed measurements of hyperfine field and Nöel temperature, when compared with similar results for a synthetic β-FeOOH sample, suggested otherwise. X-ray and chemical work suggested that the iron-containing phase in sample B is goethite, α-FeOOH in which some substitution of Al+3 for Fe3+ has occurred; the Mössbauer data are consistent with this conclusion. Both clay samples exhibited superparamagnetic behaviour and this has been utilized to obtain rough estimates of the mean radius of the particles of the iron-containing impurity. These were 117 Å for the α-Fe2O3 in sample A and 270 Å for aluminian α-FeOOH in sample B.


1971 ◽  
Vol 32 (C1) ◽  
pp. C1-863-C1-864 ◽  
Author(s):  
B. WINDOW ◽  
G. LONGWORTH ◽  
C. E. JOHNSON

1974 ◽  
Vol 35 (C6) ◽  
pp. C6-686-C6-686
Author(s):  
R. LAURENTZ ◽  
E. KLEIN ◽  
W. D. BREWER

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-783-C6-785 ◽  
Author(s):  
E. G. DA SILVA ◽  
A. ABRAS ◽  
A. O. R. SETTE CAMARA

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