Multi-Dimensional Nuclear Magnetic Resonance Methods in the Inhomogeneous Magnetic Field

<p>This thesis introduces new NMR techniques which use the inhomogeneous internal magnetic fields present in the pore space of a porous medium exposed to an external magnetic field to obtain information about the pore size and heterogeneities of the the sample. Typically internal field inhomogeneities are regarded as unwanted due to their effect on various material properties such as relaxation and diffusion. However, in the experiments presented here, we choose samples specifically for their inhomogeneous internal fields and use multi-dimensional NMR methods and simulations to obtain our pore space and heterogeneity information. We first describe software developed to specifically simulate the internal magnetic field and diffusion through the pore space of a simple sphere pack system. This software generates a sphere pack and calculates the internal magnetic field generated by z-aligned magnetic dipoles placed at the center of each sphere. The internal magnetic field gradient is also calculated in the pore space. From there, a random walk method is developed and a realistic reflection off a sphere is introduced. We work through the development of this software and the mathematics behind the algorithms used. This simulation is used in all subsequent experimental chapters. We then use a two-dimensional exchange experiment to separate the susceptibility induced line broadening with the broadening caused by diffusion through the inhomogeneous field. We observe off-diagonal line broadening as the mixing time increases. We attempt to quantify this off-diagonal growth by selecting points on either side of the off-diagonal maximum and plotting their average as a function of mixing time. A biexponential fit to the average intensities with respect to mixing time results in a characteristic time and from that a characteristic length as a fraction of bead diameter. This experiment is simulated and a biexponential growth is also observed in the simulated off-diagonal with characteristic lengths comparable to experiment. To obtain a correlation length directly from experiment and not deduce one from a characteristic time, we add a spatial dimension to our exchange experiment in the form of a propagator dimension. This dimension allows us to select 2D spectra based on their Z-displacement. We observe off-diagonal growth due to both an increase in Z-displacement and an increase in mixing time. We move away from the biexponential fit and move to a relationship based on mixing time, effective diffusion, and Z-displacement to directly calculate a characteristic length. We see these same traits in the simulated data which agrees well with experiment. Lastly, we move away from exchange experiments and move to correlating the transverse relaxation time with the internal field offset. We find that there is correlation at large magnetic field offsets and small T2 times which appear to be indicative of sample heterogeneities. To confirm this we use a highly heterogeneous rock core sample which increases the correlations seen at the previous offsets and times. This experiment is more qualitative than the previous two as we do not have a concrete value for the heterogeneity of our samples. The simulation used throughout the thesis, while showing a definite correlation between field offset and T2 relaxation, is unable to accurately simulate the experiment and requires more development.</p>

Multi-Dimensional Nuclear Magnetic Resonance Methods in the Inhomogeneous Magnetic Field

<p>This thesis introduces new NMR techniques which use the inhomogeneous internal magnetic fields present in the pore space of a porous medium exposed to an external magnetic field to obtain information about the pore size and heterogeneities of the the sample. Typically internal field inhomogeneities are regarded as unwanted due to their effect on various material properties such as relaxation and diffusion. However, in the experiments presented here, we choose samples specifically for their inhomogeneous internal fields and use multi-dimensional NMR methods and simulations to obtain our pore space and heterogeneity information. We first describe software developed to specifically simulate the internal magnetic field and diffusion through the pore space of a simple sphere pack system. This software generates a sphere pack and calculates the internal magnetic field generated by z-aligned magnetic dipoles placed at the center of each sphere. The internal magnetic field gradient is also calculated in the pore space. From there, a random walk method is developed and a realistic reflection off a sphere is introduced. We work through the development of this software and the mathematics behind the algorithms used. This simulation is used in all subsequent experimental chapters. We then use a two-dimensional exchange experiment to separate the susceptibility induced line broadening with the broadening caused by diffusion through the inhomogeneous field. We observe off-diagonal line broadening as the mixing time increases. We attempt to quantify this off-diagonal growth by selecting points on either side of the off-diagonal maximum and plotting their average as a function of mixing time. A biexponential fit to the average intensities with respect to mixing time results in a characteristic time and from that a characteristic length as a fraction of bead diameter. This experiment is simulated and a biexponential growth is also observed in the simulated off-diagonal with characteristic lengths comparable to experiment. To obtain a correlation length directly from experiment and not deduce one from a characteristic time, we add a spatial dimension to our exchange experiment in the form of a propagator dimension. This dimension allows us to select 2D spectra based on their Z-displacement. We observe off-diagonal growth due to both an increase in Z-displacement and an increase in mixing time. We move away from the biexponential fit and move to a relationship based on mixing time, effective diffusion, and Z-displacement to directly calculate a characteristic length. We see these same traits in the simulated data which agrees well with experiment. Lastly, we move away from exchange experiments and move to correlating the transverse relaxation time with the internal field offset. We find that there is correlation at large magnetic field offsets and small T2 times which appear to be indicative of sample heterogeneities. To confirm this we use a highly heterogeneous rock core sample which increases the correlations seen at the previous offsets and times. This experiment is more qualitative than the previous two as we do not have a concrete value for the heterogeneity of our samples. The simulation used throughout the thesis, while showing a definite correlation between field offset and T2 relaxation, is unable to accurately simulate the experiment and requires more development.</p>

Reconstruction of Mercury’s internal magnetic field beyond the octupole

The reconstruction of Mercury’s internal magnetic field enables us to take a look into the inner heart of Mercury. In view of the BepiColombo mission, Mercury’s magnetosphere is simulated using a hybrid plasma code and the multipoles of the internal magnetic field are estimated from the virtual spacecraft data using three distinct reconstruction methods: the truncated singular value decomposition, the Tikhonov regularization and Capon’s minimum variance projection. The study shows that a precise determination of Mercury’s internal field beyond the octupole, up to the dotriacontapole is possible and that Capon’s method provides the same high performance as the Tikhonov regularization, which is superior to the performance of the truncated singular value decomposition.

Infinite solitons in ferromagnetic materials with an internal magnetic field

The ferromagnetism induced by an external magnetic field (EMF), in (3+1) dimensions, is governed by Kraenkel–Manna–Merle system (KMMS). A (1+1) dimension model equation was derived in the literature. The magnetic moments are parallel to the magnetic field in ferromagnetism as they are aligning in the same direction of the external field. Here, it is shown that the KMMS supports the presence of internal magnetic field. This may be argued to medium characteristics. The objective of this work is to mind multiple soliton solutions, which are obtained via the generalized together with extended unified methods. Graphical representation of the results are carried. They describe infinite soliton shapes, which arise from the multiple variation of the arbitrary functions in the solutions. It is, also, shown that internal magnetic field decays, asymptotically, to zero with time.

Evaluating the Accuracy of Magnetospheric Magnetic Field Models Using Cluster Spacecraft Magnetic Field Measurements

Magnetic fields in the inner magnetosphere can be obtained as vector sums of the Earth’s own internal magnetic field and magnetic fields stemming from currents flowing in the space plasma. While the Earth’s internal magnetic field is accurately described by the International Geomagnetic Reference Field (IGRF) model, the characterization of the external magnetic fields is significantly more complicated, as they are highly variable and dependent on the actual level of the geomagnetic activity. Tsyganenko family magnetic field models (T89, T96, T01, TA15B, TA15N), parameterized by the geomagnetic activity level and solar wind parameters, are often used by the involved community to describe these fields. In the present paper, we use a large dataset (2001–2018) of magnetospheric magnetic field measurements obtained by the four Cluster spacecraft to assess the accuracy of these models. We show that, while the newer models (T01, TA15B, TA15N) perform significantly better than the old ones (T89, T96), there remain some systematic deviations, in particular at larger latitudes. Moreover, we compare the locations of the min-B equator determined using the four-point Cluster spacecraft measurements with the locations determined using the magnetic field models. We demonstrate that, despite the newer models being comparatively slightly more accurate, an uncertainty of about one degree in the latitude of the min-B equator remains.

Catalytic activity of Co-nanocrystal-doped tungsten carbide arising from an internal magnetic field

The catalytic activity of the Co-doped WC is 30% higher than that of Pt nanoparticles for the hydrogen evolution reaction arising from an internal magnetic field.