scholarly journals Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]−

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3137 ◽  
Author(s):  
Yuanbin Zhang ◽  
Yuji Sun ◽  
Tao Wang ◽  
Jiyong Liu ◽  
Bernhard Spingler ◽  
...  

The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH3]−. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.

1998 ◽  
Vol 31 (3) ◽  
pp. 173-180 ◽  
Author(s):  
WingT Liu ◽  
Kirk Marat ◽  
Ying Ren ◽  
RonaldT Eng ◽  
PuiY Wong

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