Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]−
Keyword(s):
The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH3]−. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
1987 ◽
Vol 1
(6)
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pp. 507-519
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1998 ◽
Vol 31
(3)
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pp. 173-180
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2000 ◽
Vol 73
(5)
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pp. 1143-1152
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1992 ◽
Vol 22
(3)
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pp. 275-279
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