anderson anion
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Unusual Redox Activity of the Central Heteroatom Manganese in Anderson Anion: Modulating its Oxidation State in a Gas Solid Reaction

2021 ◽  
pp. 120471
Author(s):  
Pragya Naulakha ◽  
Neeraj Kumar Mishra ◽  
N. Tanmaya Kumar ◽  
Sabbani Supriya
Keyword(s):  
Oxidation State ◽  
Redox Activity ◽  
Solid Reaction ◽  
Anderson Anion ◽  
Gas Solid Reaction

scholarly journals Fully protonated B-type hexamolybdoplatinate [H6PtMo6O24]2−and its adduct formation with [Pt(OH)6]2−

IUCrData ◽  
2017 ◽  
Vol 2 (12) ◽  
Author(s):  
Tomoji Ozeki ◽  
Atsushi Yagasaki
Keyword(s):  
Structural Analysis ◽  
Hydrogen Bonds ◽  
Adduct Formation ◽  
Linear Polymer ◽  
Anderson Anion

The crystral structure of tris(tetra-n-butylammonium) hydrogen hexahydroxidoplatinate(IV) [hexahydrogen α-hexamolybdoplatinate(IV)] pentadecahydrate, (C16H36N)3H[Pt(OH)6][H6PtMo6O24]·15H2O, was determined. The structural analysis revealed that all six triply-bridging O atoms of the hexamolybdoplatinate(IV) anion are protonated, making it formally the B-type Anderson anion [H6PtMo6O24]2−. The [H6PtMo6O24]2−anions connect with the [Pt(OH)6]2−anions through strong hydrogen bonds (O...O = 2.45–2.62 Å) to form a linear polymer in the crystal.

Sodium heteropolyhexamolybdenumnickelate (II) Na4[Ni(OH)6Mo6O18]•16H2O with an anderson anion: Synthesis and crystal structure

2015 ◽  
Vol 56 (5) ◽  
pp. 926-933 ◽  
Author(s):  
N. I. Gumerova ◽  
N. A. Melnik ◽  
G. M. Rozantsev ◽  
V. N. Baumer ◽  
S. V. Radio
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Anderson Anion
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