We prove distributional inequalities that imply the comparability of theLpnorms of the multiplicative square function ofuand the nontangential maximal function oflogu, whereuis a positive solution of a nondivergence elliptic equation. We also give criteria for singularity and mutual absolute continuity with respect to harmonic measure of any Borel measure defined on a Lipschitz domain based on these distributional inequalities. This extends recent work of M. González and A. Nicolau where the term multiplicative square functions is introduced and where the case whenuis a harmonic function is considered.