<p>Experiment values of densities and ultrasonic speed of petroleum product Gasoline (Petrol) and 2T Oil were taken in different volume concentrations from 5%, 10%------, and 95% at different temperatures from 298.15K to 318.15K having difference of 5K. From the experimental data, Apparent Molar Compressibility (<em>ϕ<sub>K</sub></em>), Relative Association (<em>R<sub>A</sub></em>), Solvation Number (<em>S<sub>n</sub></em>), Free Energy of Activation (<em>ΔE</em>), Excess Adiabatic Compressibility (<em>β<sub>ad</sub><sup>E</sup></em>), Excess Volume (<em>V<sup>E</sup></em>), Excess Free Length (<em>L<sub>f</sub><sup>E</sup></em>) have been computed. These parameters are used to focus light on the nature of component molecules of binary liquids and the excess functions are found to be sensitive to the nature and extent of the intermolecular interactions taking place in these binary mixtures.</p>