Baseline Data of Low-Density Polyethylene Continuous Pyrolysis for Liquid Fuel Manufacture

The recycling of end-of-life plastics is a problem, since small parts can be returned into circulation. The rest is burned, landfilled or recycled into low-quality heating oil by pyrolysis methods. The disadvantages of this method are the need to dispose the formed by-product, pyrolytic carbon, the poor quality of produced liquid fuel and the low productivity of the method associated with the periodicity of the process. In this work, methods of thermogravimetry and chromatography–mass spectrometry (GC-MS) have been used to study the co-pyrolysis products of low-density polyethylene (LDPE) and oxygen-containing substances at the pressures of 4–8 MPa and temperatures of 520–620 °C. Experiments have highlighted the conditions needed for producing of high-quality liquid fuel. Initial data have been prepared for the design of a continuous pyrolysis reactor to dispose polymer waste for the production of bio-oil which would be available to enter the petrochemical products market.

High-pressure compacted recycled polymeric composite waste materials for marine applications

Abstract Options for recycling fiber composite polymer (FCP) materials are scarce, as these materials cannot be normally recycled and are toxic when improperly disposed. Additionally, reducing water usage is an increasing concern, as the concrete industry currently uses 10% of the world’s industrial water. Therefore, building upon our previous work, this research explores the use of polymer hybrid carbon and glass composite waste products as reinforcements in high-pressure compacted cement. Our material used nearly 70% less water during manufacturing and exhibited improved durability and salt corrosion resistance. Compression strength tests were performed on high-pressure compacted materials containing 6.0 wt% recycled admixtures before and after saltwater aging, and the results showed that the material retained 90% of its original compression strength after aging, as it contained fewer pores and cavities. Our experimental work was supplemented by molecular dynamics. Simulations, which indicated that the synergetic effects of compaction and FCP admixture addition slowed the diffusion of corrosive salt ions by an average of 84%. Thus, our high-pressure compacted cement material may be suitable for extended use in marine environments, while also reducing the amount of commercial fiber composite polymer waste material that is sent to the landfill. Article Highlights Fiber composite waste was successfully recycled into denser, high-pressure compacted ordinary Portland cement materials. High-pressure compacted cement samples containing 6% recycled admixtures retained 90% of their compression strength after salt aging. The high-pressure compaction method utilized 70% less water during specimen fabrication.

A facile and sustainable one-pot approach to the aqueous and low-temperature PET-to-UiO-66(Zr) upcycling

Accelerating waste management requires the conversion of polymer waste to value-added materials through sustainable approaches. While depolymerised PET has been used as feedstock to produce metal-organic frameworks, this is the...

JUSTIFICATION OF METHODS OF POLYMERIC WASTE PROCESSING IN AGRICULTURAL PRODUCTION

The development of industry has led to the unlimited technological application of polymers, ranging from plastic bags, rubber, fabrics, paper and other materials. Displacing traditional materials, polymer products began to be used in agriculture. Polymers are used to make films for soil cover (mulching), anti-hail nets, shaft bushings, gears, body parts, tanks for storage and transportation of fertilizers and working fluids and many other parts. The operational properties of polymer products are becoming more and more perfect, but at the same time the methods of polymer waste management and their utilization are being developed and complicated. Over time, they can no longer be used for their intended purpose, so they are discarded and sent to landfills, while polymers are valuable structural materials and their reuse will not only be positive for the environment, but can also become a profitable branch of the agro-industrial complex. Pellet production is one of the methods of recycling polymer waste, which in the future can be used for the production of new parts, as well as added to the composition of composite materials based on organic or mineral fillers. This article examines the problem of recycling polymer waste by improving their processing technologies. The analysis of existing methods of utilization and processing of polymeric waste generated in agriculture is carried out. Determination of physical and mechanical properties of polymer waste, in particular thermoplastics. Taking into account the received information, conclusions are made and the analysis of methods of utilization and processing of polymeric waste in secondary raw materials is carried out.

Biotesting of polymeric waste excluded from solid waste waste

Introduction. Annually, the volume of accumulated polymers in landfills in Ukraine is growing by more than 1 million tons, but the volume of recycled polymer packaging over the past ten years has not exceeded 3%. The goal is to establish the degree of toxicological impact on biosphere objects of polymers extracted from solid waste, to assess the safety of using household polymer waste as a secondary raw material for further processing. The task is to establish the degree of biological and toxicological safety of polymer wastes extracted from solid waste. Methods and techniques: toxicological - determination of water toxicity on acute Daphnia magna according to DSTU 4173: 2003 (ISO 6341: 1996, MOD) and chronic according to DSTU 4166: 2003 (ISO 10706: 2000, MOD), and Paramecium caudatum ciliates, soil microflora reactions (saprotrophic soil bacteria CFU / g) according to MR 2609-82, the assessment of phytotoxic effects on higher plants was carried out by vegetation methods according to ISO 17402-2008, ISO 17126-2005a, ISO 22030: 2005b, ISO 11269 -1:2012a. Results. The research results show that aqueous extracts from waste polymers extracted from solid waste and their mixture do not have a pronounced toxic effect on aquatic organisms. There is no significant effect on soil bacteria. The study of the effect of polymer waste on seed germination did not reveal phytotoxic effects for any crop. A slight phytotoxic effect was observed during the study of PVC and PS waste. Wheat and mustard were the most sensitive. The level of phytotoxic effect was within acceptable limits and did not exceed 5.67%. Evaluation of phytotoxic effects on stem length showed the presence of effects from all processed products except PVC. The impact, characterized as weak, ranged from - 2.06% (PP) to - 13.27% (PS). The effect on root length was found for samples with PS waste (-7.23%), which was characterized as weak and PVC (-43.52%) - medium. Watercress and mustard were the most sensitive plants to the effects of polymer waste. Conclusions. The studied samples of polymer waste do not show hygienically significant toxic effects on water and soil test objects, even in concentrations of 1: 1, so the impact on the above test organisms polymer waste removed from solid waste is classified as hazard class 4. According to the assessment of phytotoxic effect, polymer waste removed from solid waste is classified as hazard class 4, except for PVC - hazard class 3.

Polymer waste safe disposal by incineration in electrostatic field

Polymer waste disposal of is one of the most pressing problems of our time. The incineration method is widespread, but it has its drawbacks. Problems during the polymer waste combustion, which include low combustion efficiency, combustion products toxicity, significantly reduce the possibility of waste disposal incinerators using. In this regard, the work considers the use of an electrostatic field to optimize the combustion process. Experimental studies of the electrostatic field influence on the substances difficult for disposal (polyethylene, polypropylene, polystyrene, rubber) combustion have been carried out. The possibility of increasing the polymer waste combustion rate, flame temperature, and combustion efficiency is shown.

Modification of a bituminous binder using waste products from the polymer industry

In this paper, we have investigated the possibilities of the modification of bituminous mixtures using recycled plastic. Waste from enterprises that process plastic is a serious danger to the environment, which is why the need to develop technologies for their processing is not in doubt. The economic advantages of using such additives are that the modifier used is the total waste of industrial enterprises that manufacture products from thermoplastics. Thus, it is possible to solve several problems at once: reducing the cost of production of bitumen; improvement of their physical and chemical characteristics and recycling of non-recycled waste. Patent information on the use of thermoplastics as a bitumen modifier was analyzed. During the work, waste from the extrusion industry of high-pressure polyethylene (LDPE) used. The influence of additives on the basic physical parameters of bitumen is shown. In the course of research, it was found that the addition of 2-3% polymers to the original formulation allows us to obtain bitumen, the main physical parameters of which (penetration, ductility, softening) meet the existing requirements. With this method of bitumen modification, the cost of their production is reduced without deterioration of the properties of the finished product. We also investigated the possibility of introducing up to 25% modifiers into the formulation, for maximum utilization of polymer waste. The bitumen obtained in this way can be used in regions with a hot climate. An important fact is the unification of the method of introducing additives into the existing technology, which does not require its change. The results of the study showed that thanks to the results obtained, it is possible to significantly reduce the cost of producing asphalt and bitumen products, expand the technological properties of finished road surfaces, and solve the problem of recycling plastic waste.

Effect of Recycled Polymer Waste on Paraffinic Oil

Plastics has become the necessity of our daily life. Its production and consumption has been rising rapidly due to its wide range of application in the domestic and industrial usage. But due to its non-biodegradable nature, it cannot be easily decomposed in the environment and hence is a major issue of Environment pollution. So, nowadays new technology is being used to treat the waste plastic by a known chemical reaction - pyrolysis. Under the pyrolytic conditions and cracking process, the plastic wastes can be decomposed into three different states thereby the converted product can be reused in different processes. The waste plastics consisting of high-density polyethylene (HDPE) was pyrolyzed using catalyst and the recovered crude was analyzed and used as flow improvers. The liquid hydrocarbons obtained from the Pyrolysis of waste polymer products was used as diluent to change the characteristics of crude oil. The aim of the research work is to evaluate the change in the flow when blended with the Crude oil of different place. The Crude oil was Blended with the recycled diluents were in different fractions of 5%, 15%, and 25% of diluent. The plastic pyrolysis oil were then tested in a with fractions of 5, 10 and 15 volume% of diluent and their performance and characteristics analyzed and compare with it. Keywords: Catalyst, Paraffinic Oil, Recycled waste, Pour Point, Blended Oil