Catalysis of Electrophilic Reactions by Proton Loss from a Coordinated Ligand

2007 ◽  
pp. 11-13
Author(s):  
J. Halpern
Keyword(s):  
Electrophilic Reactions ◽  
Proton Loss

On the Reactivity of mRNA Caps: C-H Oxidative Addition of 7-Methylguanosine to Pt(0)

2019 ◽  
Author(s):  
Maria Ines Leitao ◽  
Carmen Gonzalez ◽  
Zuzanna Filipiak ◽  
Ana Petronilho
Keyword(s):  
Oxidative Addition ◽  
Carbene Complex ◽  
Proton Loss

<p>7-methylguanosine, the so-called mRNA cap 0 bears a very labile C8-H bond, due to the formation of an ylide/N-heterocyclic carbene, upon proton loss. The reaction of 7-methylguanosine with Pt(PPh3)4, via C-H oxidative addition, yields a hydrido–PtII carbene complex and this reactivity can be extrapolated to 7,9-dimethylguanine. </p>

Carbenoids with neighboring heteroatoms. III. Electrophilic reactions of two .alpha.-halocyclopropyllithium compounds

1972 ◽  
Vol 37 (15) ◽  
pp. 2436-2443 ◽  
Author(s):  
K. Grant. Taylor ◽  
W. Edward. Hobbs ◽  
Melvin S. Clark ◽  
James. Chaney
Keyword(s):  
Electrophilic Reactions

Electrophilic Reactions of Skin-Sensitizing Sultones

2007 ◽  
Vol 20 (1) ◽  
pp. 61-71 ◽  
Author(s):  
David W. Roberts ◽  
Douglas L. Williams ◽  
Donald Bethell
Keyword(s):  
Electrophilic Reactions

ChemInform Abstract: Electrophilic Reactions at Single Bonds. Part 25. Nitration of Adamantane and Diamantane with Nitronium Tetrafluoroborate.

ChemInform ◽  
2010 ◽  
Vol 24 (49) ◽  
pp. no-no
Author(s):  
G. A. OLAH ◽  
P. RAMAIAH ◽  
C. B. RAO ◽  
G. SANDFORD ◽  
R. GOLAM ◽  
...  
Keyword(s):  
Electrophilic Reactions ◽  
Single Bonds ◽  
Nitronium Tetrafluoroborate

ChemInform Abstract: Chlorinations by Hypochlorous Acid - Free-Radical versus Electrophilic Reactions

ChemInform ◽  
1989 ◽  
Vol 20 (15) ◽  
Author(s):  
F. MINISCI ◽  
E. VISMARA ◽  
F. FONTANA ◽  
E. PLATONE ◽  
G. FARACI
Keyword(s):  
Free Radical ◽  
Hypochlorous Acid ◽  
Electrophilic Reactions
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