Selective Oxidation of Aromatic Amines to Nitro Derivatives using Potassium Iodide-tert-Butyl Hydroperoxide Catalytic System

2009 ◽  
Vol 351 (1-2) ◽  
pp. 93-96 ◽  
Author(s):  
K. Rajender Reddy ◽  
C. Uma Maheswari ◽  
M. Venkateshwar ◽  
M. Lakshmi Kantam
Keyword(s):  
Selective Oxidation ◽  
Catalytic System ◽  
Potassium Iodide ◽  
Aromatic Amines ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide ◽  
Nitro Derivatives

Selective oxidation of aromatic aldehydes to arenecarboxylic acids using ebselen-tert-butyl hydroperoxide catalytic system

Tetrahedron ◽  
2001 ◽  
Vol 57 (48) ◽  
pp. 9743-9748 ◽  
Author(s):  
Halina Wójtowicz ◽  
Monika Brząszcz ◽  
Krystian Kloc ◽  
Jacek Młochowski
Keyword(s):  
Selective Oxidation ◽  
Catalytic System ◽  
Aromatic Aldehydes ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Cobalt-Catalyzed Oxidative α-Cyanation of Tertiary Aromatic Amines with Trimethylsilyl Cyanide and tert-Butyl Hydroperoxide

Synlett ◽  
2013 ◽  
Vol 24 (10) ◽  
pp. 1283-1285 ◽  
Author(s):  
Norio Sakai ◽  
Akihiro Mutsuro ◽  
Reiko Ikeda ◽  
Takeo Konakahara
Keyword(s):  
Aromatic Amines ◽  
Butyl Hydroperoxide ◽  
Trimethylsilyl Cyanide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Ni-Catalyzed Oxidative Transamidation of Tertiary Aromatic Amines with N-Acyl Saccharin

Synlett ◽  
2021 ◽  
Author(s):  
Shengzhang Liu ◽  
Lingyun Yang ◽  
Jiasi Tao ◽  
Weijie Yu ◽  
Tao Wang ◽  
...  
Keyword(s):  
Aromatic Amines ◽  
Secondary Amines ◽  
Tertiary Amines ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Employment of tertiary amines as the surrogates for secondary amines has prominent superiority in stabilization and easy handle. Herein, a Ni-catalyzed transamidation of N-acyl saccharin amides with tertiary aromatic amines has been reported. By using tert-butyl hydroperoxide (TBHP) as the terminal oxidant, this reaction is featured with a selective cleavage of the C(sp3)–N bonds of the unsymmetrical tertiary aromatic amines depending on the sizes of the alkyl substituents.

Catalytic System Based on Triphenylantimony and tert-Butyl Hydroperoxide for the Heck Reaction

ChemInform ◽  
2004 ◽  
Vol 35 (15) ◽  
Author(s):  
D. V. Moiseev ◽  
A. V. Gushchin ◽  
V. A. Morugova ◽  
V. A. Dodonov
Keyword(s):  
Catalytic System ◽  
Heck Reaction ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

ChemInform Abstract: Mild and Efficient Oxy-Iodination of Alkynes and Phenols with Potassium Iodide and tert-Butyl Hydroperoxide.

ChemInform ◽  
2010 ◽  
Vol 41 (30) ◽  
pp. no-no
Author(s):  
K. Rajender Reddy ◽  
M. Venkateshwar ◽  
C. Uma Maheswari ◽  
P. Santhosh Kumar
Keyword(s):  
Potassium Iodide ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide
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