Electronic Effects of Linker Substitution on Lewis Acid Catalysis with Metal-Organic Frameworks

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Bimetallic Zr(Ti)-NDC based metal–organic frameworks (MOFs) have been prepared by incorporation of titanium(iv) into zirconium(iv)-NDC-MOFs (UiO family).


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Superstable 3p-block MOF platforms exhibit excellent gas uptake and separation performance, and prominent Lewis acid catalysis for CO2 fixation.


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