scholarly journals Inside Cover: 4.5 V High‐Voltage Rechargeable Batteries Enabled by the Reduction of Polarization on the Lithium Metal Anode (Angew. Chem. Int. Ed. 43/2019)

2019 ◽  
Vol 58 (43) ◽  
pp. 15164-15164
Author(s):  
Chong Yan ◽  
Rui Xu ◽  
Jin‐Lei Qin ◽  
Hong Yuan ◽  
Ye Xiao ◽  
...  
Keyword(s):  
High Voltage ◽  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

4.5 V High‐Voltage Rechargeable Batteries Enabled by the Reduction of Polarization on the Lithium Metal Anode

2019 ◽  
Vol 131 (43) ◽  
pp. 15379-15382 ◽  
Author(s):  
Chong Yan ◽  
Rui Xu ◽  
Jin‐Lei Qin ◽  
Hong Yuan ◽  
Ye Xiao ◽  
...  
Keyword(s):  
High Voltage ◽  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

4.5 V High‐Voltage Rechargeable Batteries Enabled by the Reduction of Polarization on the Lithium Metal Anode

2019 ◽  
Vol 58 (43) ◽  
pp. 15235-15238 ◽  
Author(s):  
Chong Yan ◽  
Rui Xu ◽  
Jin‐Lei Qin ◽  
Hong Yuan ◽  
Ye Xiao ◽  
...  
Keyword(s):  
High Voltage ◽  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Innentitelbild: 4.5 V High‐Voltage Rechargeable Batteries Enabled by the Reduction of Polarization on the Lithium Metal Anode (Angew. Chem. 43/2019)

2019 ◽  
Vol 131 (43) ◽  
pp. 15306-15306
Author(s):  
Chong Yan ◽  
Rui Xu ◽  
Jin‐Lei Qin ◽  
Hong Yuan ◽  
Ye Xiao ◽  
...  
Keyword(s):  
High Voltage ◽  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

2017 ◽  
Vol 117 (15) ◽  
pp. 10403-10473 ◽  
Author(s):  
Xin-Bing Cheng ◽  
Rui Zhang ◽  
Chen-Zi Zhao ◽  
Qiang Zhang
Keyword(s):  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Mesoporous Graphene Hosts for Dendrite-Free Lithium Metal Anode in Working Rechargeable Batteries

2020 ◽  
Vol 26 (2) ◽  
pp. 127-134 ◽  
Author(s):  
He Liu ◽  
Xinbing Cheng ◽  
Rui Zhang ◽  
Peng Shi ◽  
Xin Shen ◽  
...  
Keyword(s):  
Rechargeable Batteries ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Suppressing electrolyte-lithium metal reactivity via Li+-desolvation in uniform nano-porous separator

2022 ◽  
Vol 13 (1) ◽  
Author(s):  
Li Sheng ◽  
Qianqian Wang ◽  
Xiang Liu ◽  
Hao Cui ◽  
Xiaolin Wang ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
High Voltage ◽  
Metal Electrode ◽  
Dendrite Growth ◽  
Lithium Metal ◽  
Metal Anode ◽  
Effective Suppression ◽  
Lithium Metal Anode

AbstractLithium reactivity with electrolytes leads to their continuous consumption and dendrite growth, which constitute major obstacles to harnessing the tremendous energy of lithium-metal anode in a reversible manner. Considerable attention has been focused on inhibiting dendrite via interface and electrolyte engineering, while admitting electrolyte-lithium metal reactivity as a thermodynamic inevitability. Here, we report the effective suppression of such reactivity through a nano-porous separator. Calculation assisted by diversified characterizations reveals that the separator partially desolvates Li+ in confinement created by its uniform nanopores, and deactivates solvents for electrochemical reduction before Li0-deposition occurs. The consequence of such deactivation is realizing dendrite-free lithium-metal electrode, which even retaining its metallic lustre after long-term cycling in both Li-symmetric cell and high-voltage Li-metal battery with LiNi0.6Mn0.2Co0.2O2 as cathode. The discovery that a nano-structured separator alters both bulk and interfacial behaviors of electrolytes points us toward a new direction to harness lithium-metal as the most promising anode.

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