Main-chain chiral smectic liquid-crystalline ionomers containing sulfonic acid groups

2005 ◽  
Vol 99 (3) ◽  
pp. 1254-1263 ◽  
Author(s):  
Mei Tian ◽  
Bao-Yan Zhang ◽  
Fan-Bao Meng ◽  
Bao-Ling Zang
2008 ◽  
Vol 110 (2) ◽  
pp. 791-797 ◽  
Author(s):  
Qian-Yue Li ◽  
Fan-Bao Meng ◽  
Bao-Yan Zhang ◽  
Mei Tian ◽  
Jiao Lian

2013 ◽  
Vol 385-386 ◽  
pp. 39-42
Author(s):  
Zhi Xin Xu ◽  
Li Gao ◽  
Dan Shu Yao ◽  
Xiao Zhi He ◽  
Mei Tian

Polymer ◽  
2003 ◽  
Vol 44 (14) ◽  
pp. 3935-3943 ◽  
Author(s):  
Fanbao Meng ◽  
Baoyan Zhang ◽  
Lumei Liu ◽  
Baoling Zang

2017 ◽  
Vol 30 (4) ◽  
pp. 437-445 ◽  
Author(s):  
Wadi Elim Sosa-González ◽  
Ramón del Jesús Palí-Casanova ◽  
Yamile Pérez-Padilla ◽  
María Isabel Loría-Bastarrachea ◽  
José Luis Santiago-García ◽  
...  

Several aromatic sulfonated copoly(ether–amide)s, based on the aromatic diamines 4,4′-(hexafluoroisopropylidene)bis(p-phenyleneoxy)-dianiline (HFD) and 2,4-diaminobenzensulfonic acid (DABS) and 4,4′-oxybis(benzoic acid) (OBA), were synthesized through a polycondensation reaction. The sulfonation degree was controlled by introducing different concentrations of 2,4-DABS from 40 mol% up to 80 mol%. Proton nuclear magnetic resonance validated the expected concentrations of sulfonic acid groups in the sulfonated aromatic copoly(ether–amide)s. Thermal decomposition of sulfonic groups was found to initiate at 280°C, while main chain decomposition initiates at 410°C. Proton conductivity between 30°C and 75°C was 19.0 and 45.0 mS/cm, respectively, for the copolymer with the highest concentration of sulfonic groups (–SO3H). Comparison with structurally similar sulfonated copolyamides and copoly(ether–amide)s indicates that these new sulfonated copoly(ether–amide)s based on 4,4′-OBA show improved mechanical properties, but a decrease in ion exchange capacity and proton conductivity.


2008 ◽  
Vol 19 (9) ◽  
pp. 1242-1249 ◽  
Author(s):  
Fan-Bao Meng ◽  
Yan-Hui Sun ◽  
Yong-Mei Gao ◽  
Xian-Gen Song ◽  
Bao-Yan Zhang

2003 ◽  
Vol 36 (9) ◽  
pp. 3320-3326 ◽  
Author(s):  
Bao-Yan Zhang ◽  
Fan-Bao Meng ◽  
Bao-Ling Zang ◽  
Jian-she Hu

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