Abstract
Radiation stability is one of the key properties to enable the efficient use of extractants in spent nuclear fuel with high radioactivity. The last several decades have witnessed a rapid progress in the radiation chemistry of extractants. A variety of studies and reviews pertinent to the radiation stability of extractants have been published. However, a thorough summary for the alpha radiolysis results of extractants is not available. In this review, we survey the development of alpha radiolysis of extractants for actinide lanthanide separation and compare their radiolysis behaviors induced by alpha particles and gamma rays. The discussion of alpha radiolysis of extractants is divided into three parts according to the functional groups of extractants (i.e., phosphine oxide, amide and bis-triazinyl bipyridines). Given the importance of radiation source to carry out alpha irradiation experiment, we first give a brief introduction to three practicable alpha radiation sources including alpha emitting isotopes, helium ion beam and reactor. We hope this review will provide useful information and unleash a broad palette of opportunities for researchers interested in radiation chemistry.
Evidence of Alpha Radiolysis in the Formation of a Californium Nitrate Complex
