ChemInform Abstract: INVESTIGATIONS OF STRUCTURE AND CONFORMATION PART 4, AN ELECTRON SPIN RESONANCE AND INDO MOLECULAR ORBITAL STUDY OF THE INFLUENCE OF ELECTRONIC INTERACTIONS UPON RADICAL GEOMETRY

1975 ◽  
Vol 6 (11) ◽  
Author(s):  
BRUCE C. GILBERT ◽  
MICHAEL TRENWITH ◽  
ANTHONY J. DOBBS
Keyword(s):  
Electron Spin Resonance ◽  
Molecular Orbital ◽  
Electron Spin ◽  
Electronic Interactions ◽  
Molecular Orbital Study ◽  
Orbital Study ◽  
Spin Resonance

Electron resonance studies of transition metal oxyions, I. Experimental results for the manganate, hypomanganate and ferrate ions

1960 ◽  
Vol 254 (1276) ◽  
pp. 101-110 ◽  
Keyword(s):  
Electron Spin Resonance ◽  
Transition Metal ◽  
Single Crystals ◽  
Molecular Orbital ◽  
Electron Spin ◽  
Potassium Chromate ◽  
Tetrahedral Structure ◽  
Spin Hamiltonians ◽  
Spin Resonance ◽  
Qualitative Nature

Detailed electron spin resonance studies of single crystals of potassium chromate containing manganate and ferrate ions and of potassium orthovanadate containing hypom anganate ions are described and the appropriate spin Hamiltonians are determined. The results confirm the tetrahedral structure of these ions and the assignation of spin S = 1 to ferrate and hypomanganate. A discussion of the qualitative nature of the results shows that the unpaired electrons in these ions occupy a doubly degenerate molecular orbital.

Sign in / Sign up

Export Citation Format

Share Document