ChemInform Abstract: ELECTROCHEMICAL OXIDATION. VII. SYNTHESIS AND STRUCTURE OF 7-TERT-BUTYL-2-METHYLBENZOXAZOLES

1982 ◽  
Vol 13 (16) ◽  
Author(s):  
E.-L. DREHER ◽  
J. BRACHT ◽  
M. EL-MOBAYED ◽  
P. HUETTER ◽  
W. WINTER ◽  
...  
1977 ◽  
Vol 81 (1) ◽  
pp. 171-187 ◽  
Author(s):  
Jeffrey A. Richards ◽  
Dennis H. Evans

1985 ◽  
Vol 33 (9) ◽  
pp. 4007-4011 ◽  
Author(s):  
HIDENOBU OHMORI ◽  
CHIHIRO UEDA ◽  
YOSHIMI TOKUNO ◽  
HATSUO MAEDA ◽  
MASAICHIRO MASUI

1988 ◽  
Vol 66 (1) ◽  
pp. 35-44 ◽  
Author(s):  
Jean-Yves Huot ◽  
Denis Serve ◽  
Sylvie Desjardins ◽  
Jean Lessard

The electrochemical oxidation of [amide-Ag-amide]Ag, [amide-Ag-amide]Et4N, and [amide]Et4N salts of imides and formanilides, in acetonitrile containing tetraethylammonium tetrafluoroborate, at platinum and vitreous carbon electrodes, is a one-electron and irreversible (αn < 1) process leading to an amidyl radicals that preferentially abstracts hydrogen from the medium to give the parent amide. N,N-Coupling (formation of hydrazine derivatives) was observed in the oxidation of the amide-Ag-amide anions of formanilide and p-methoxyformanilide. No coupling was observed in the oxidation of the amide-Ag-amide anion of p-cyanoformanilide and of imides, and in the oxidation of any of the tetraethylammonium salts (amidyl anions) studied. The formanilidyl radical was trapped by N-tert-butyl-α-phenylnitrone. Attempts to trap the succinimidyl radical by addition to olefins were unsuccessful.


1986 ◽  
Vol 17 (12) ◽  
Author(s):  
H. OHMORI ◽  
C. UEDA ◽  
Y. TOKUNO ◽  
H. MAEDA ◽  
M. MASUI

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