Dynamic Metasomatism Experiments Investigating the Interaction between Migrating Potassic Melt and Garnet Peridotite

Dynamic metasomatism experiments were performed by reacting a lamproite melt with garnet peridotite by drawing melt through the peridotite into a vitreous carbon melt trap, ensuring the flow of melt through the peridotite and facilitating analysis of the melt. Pressure (2–3 GPa) and temperature (1050–1125 °C) conditions were chosen where the lamproite was molten but the peridotite was not. Phlogopite was formed and garnet and orthopyroxene reacted out, resulting in phlogopite wehrlite (2 GPa) and phlogopite harzburgite (3 GPa). Phlogopites in the peridotite have higher Mg/(Mg + Fe) and Cr2O3 and lower TiO2 than in the lamproite due to buffering by peridotite minerals, with Cr2O3 from the elimination of garnet. Compositional trends in phlogopites in the peridotite are similar to those in natural garnet peridotite xenoliths in kimberlites. Changes in melt composition resulting from the reaction show decreased TiO2 and increased Cr2O3 and Mg/(Mg + Fe). The loss of phlogopite components during migration through the peridotite results in low K2O/Na2O and K/Al in melts, indicating that chemical characteristics of lamproites are lost through reaction with peridotite so that emerging melts would be less extreme in composition. This indicates that lamproites are unlikely to be derived from a source rich in peridotite, and more likely originate in a source dominated by phlogopite-rich hydrous pyroxenites. Phlogopites from an experiment in which lamproite and peridotite were intimately mixed before the experiment did not produce the same phlogopite compositions, showing that care must be taken in the design of reaction experiments.

Vitreous Carbon, Geometry and Topology: A Hollistic Approach

Glass-like carbon (GLC) is a complex structure with astonishing properties: isotropic sp2 structure, low density and chemical robustness. Despite the expanded efforts to understand the structure, it remains little known. We review the different models and a physical route (pulsed laser deposition) based on a well controlled annealing of the native 2D/3D amorphous films. The many models all have compromises: neither all bad nor entirely satisfactory. Properties are understood in a single framework given by topological and geometrical properties. To do this, we present the basic tools of topology and geometry at a ground level for 2D surface, graphene being the best candidate to do this. With this in mind, special attention is paid to the hyperbolic geometry giving birth to triply periodic minimal surfaces. Such surfaces are the basic tools to understand the GLC network architecture. Using two theorems (the classification and the uniformisation), most of the GLC properties can be tackled at least at a heuristic level. All the properties presented can be extended to 2D materials. It is hoped that some researchers may find it useful for their experiments.

Reactive and Inelastic Scattering Dynamics of Hyperthermal O and O2 from a Carbon Fiber Network

The reactive and inelastic scattering dynamics of ground-state atomic and molecular oxygen from a carbon fiber network at 1023-1823 K was investigated with a molecular beam-surface scattering technique. A molecular beam containing hyperthermal O and O₂ with a mole ratio of 0.92:0.08 and nominal velocity of 8 km s^-1 was directed at the network, and time-of-flight distributions of the scattered products were collected at various angles with the use of a rotatable mass spectrometer detector. O atoms exhibited both impulsive scattering (IS) and thermal desorption (TD) dynamics, where the TD O-atom flux increased with surface temperature and the IS O-atom flux remained relatively constant. While the majority of the TD O atoms desorbed promptly after the beam pulse struck the network, signatures of thermal processes occurring over long residence times were also observed. Evidence of O₂ reactions was not observed, and the behavior of the inelastically scattered O₂ was invariant to the temperature of the network and showed both IS and TD dynamics. The dominant reactive product was CO, whereas CO₂ was a minor product. Both these products showed only TD dynamics. The observed flux of CO initially increased with temperature and then reached a plateau above which the flux no longer increased with temperature, over the temperature range studied. Thermally desorbed CO products exited the network promptly or after relatively long residence times, and two populations of CO with long residence times were distinguished. Hysteresis was observed in the temperature-dependent flux of thermally desorbed O and CO, with opposing trends for the two products. This work follows similar studies in our laboratory where the target materials were vitreous carbon and highly oriented pyrolytic graphite. The data suggest that the chemical reactivity of the three forms of <i>sp</i>² carbon surfaces is similar and that the differences arise from the variations of the morphology. <br>

Reactive and Inelastic Scattering Dynamics of Hyperthermal O and O2 from a Carbon Fiber Network

The reactive and inelastic scattering dynamics of ground-state atomic and molecular oxygen from a carbon fiber network at 1023-1823 K was investigated with a molecular beam-surface scattering technique. A molecular beam containing hyperthermal O and O₂ with a mole ratio of 0.92:0.08 and nominal velocity of 8 km s^-1 was directed at the network, and time-of-flight distributions of the scattered products were collected at various angles with the use of a rotatable mass spectrometer detector. O atoms exhibited both impulsive scattering (IS) and thermal desorption (TD) dynamics, where the TD O-atom flux increased with surface temperature and the IS O-atom flux remained relatively constant. While the majority of the TD O atoms desorbed promptly after the beam pulse struck the network, signatures of thermal processes occurring over long residence times were also observed. Evidence of O₂ reactions was not observed, and the behavior of the inelastically scattered O₂ was invariant to the temperature of the network and showed both IS and TD dynamics. The dominant reactive product was CO, whereas CO₂ was a minor product. Both these products showed only TD dynamics. The observed flux of CO initially increased with temperature and then reached a plateau above which the flux no longer increased with temperature, over the temperature range studied. Thermally desorbed CO products exited the network promptly or after relatively long residence times, and two populations of CO with long residence times were distinguished. Hysteresis was observed in the temperature-dependent flux of thermally desorbed O and CO, with opposing trends for the two products. This work follows similar studies in our laboratory where the target materials were vitreous carbon and highly oriented pyrolytic graphite. The data suggest that the chemical reactivity of the three forms of <i>sp</i>² carbon surfaces is similar and that the differences arise from the variations of the morphology. <br>

Reactive and Inelastic Scattering Dynamics of Hyperthermal O and O2 from a Carbon Fiber Network

The reactive and inelastic scattering dynamics of ground-state atomic and molecular oxygen from a carbon fiber network at 1023-1823 K was investigated with a molecular beam-surface scattering technique. A molecular beam containing hyperthermal O and O₂ with a mole ratio of 0.92:0.08 and nominal velocity of 8 km s^-1 was directed at the network, and time-of-flight distributions of the scattered products were collected at various angles with the use of a rotatable mass spectrometer detector. O atoms exhibited both impulsive scattering (IS) and thermal desorption (TD) dynamics, where the TD O-atom flux increased with surface temperature and the IS O-atom flux remained relatively constant. While the majority of the TD O atoms desorbed promptly after the beam pulse struck the network, signatures of thermal processes occurring over long residence times were also observed. Evidence of O₂ reactions was not observed, and the behavior of the inelastically scattered O₂ was invariant to the temperature of the network and showed both IS and TD dynamics. The dominant reactive product was CO, whereas CO₂ was a minor product. Both these products showed only TD dynamics. The observed flux of CO initially increased with temperature and then reached a plateau above which the flux no longer increased with temperature, over the temperature range studied. Thermally desorbed CO products exited the network promptly or after relatively long residence times, and two populations of CO with long residence times were distinguished. Hysteresis was observed in the temperature-dependent flux of thermally desorbed O and CO, with opposing trends for the two products. This work follows similar studies in our laboratory where the target materials were vitreous carbon and highly oriented pyrolytic graphite. The data suggest that the chemical reactivity of the three forms of <i>sp</i>² carbon surfaces is similar and that the differences arise from the variations of the morphology. <br>