ChemInform Abstract: Axially Asymmetric Metal Alkyls. Part 3. Chemical, Electrochemical, and Structural Studies of Group 5A d0,1,2Metallepines.

The single-crystal X-ray structural characterization of λ-(R,R)-and δ- (S,S)-[ ZrL (η-C5H5)2], L = [2-CH(SiMe3)C6H4]22-, is recorded for comparison with the λ-(R,S)-/δ-(S,R)-isomer, previously reported.

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Axially asymmetric metal alkyls. Part 1. Lithium alkyls of 2,2′-dimethylbiphenyl and its trimethylsilylmethylated compounds: crystal structures of [{Li(Me2NCH2CH2NMe2)}2{(2-CHRC6H4)2}] for R = H (polymeric) and R = SiMe3(monomeric)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9840000321 ◽

1984 ◽

pp. 321-330 ◽

Cited By ~ 17

Author(s):

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Colin L. Raston ◽

Paul Twiss ◽

Allan H. White

Keyword(s):

Crystal Structures ◽

Axially Asymmetric ◽

Metal Alkyls

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ChemInform Abstract: AXIALLY ASYMMETRIC METAL ALKYLS. PART 1. LITHIUM ALKYLS OF 2,2′-DIMETHYLBIPHENYL AND ITS TRIMETHYLSILYLMETHYLATED COMPOUNDS: CRYSTAL STRUCTURES OF α,α′-BIS((N,N,N′,N′-TETRAMETHYLETHYLENEDIAMINE)LITHIO)-2,2′-DIMETHY# LBIPHENYL AND -2,2

Chemischer Informationsdienst ◽

10.1002/chin.198423264 ◽

1984 ◽

Vol 15 (23) ◽

Author(s):

L. M. ENGELHARDT ◽

W.-P. LEUNG ◽

C. L. RASTON ◽

P. TWISS ◽

A. H. WHITE

Keyword(s):

Crystal Structures ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 2. Synthesis of the di-Grignard reagent [{Mg(thf)nCl}2R][thf = tetrahydrofuran, R =(2-CH2C6H4)22–] and 6,7-dihydro-5H-dibenzo[c,e]-silepines and -stannepines; X-ray crystal structures of [SnPh2R] and δ-SS- and λ-RR-[SnPh2{[2-CH(SiMe3)C6H4]2}]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9840000331 ◽

1984 ◽

pp. 331-340 ◽

Cited By ~ 9

Author(s):

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Colin L. Raston ◽

Paul Twiss ◽

Allan H. White

Keyword(s):

Crystal Structures ◽

Grignard Reagent ◽

X Ray ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 5. Synthesis and reduction to ZrIIIspecies of Group 4 metallepines [ML(η-C5H5)2][L =(2-CHRC6H4)22–, R = H, M = Ti, Zr, or Hf)], isomers of [ZrL(η-C5H5)2](R = SiMe3), and meso-[M{1,8-(CHSiMe3)2C10H6}(η-C5H5)2](M = Zr or Hf); X-ray crystal structures of [TiL(η-C5H5)2](R = H) and λ- and δ-RS-[ZrL(η-C5H5)2](R = SiMe3)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9870002347 ◽

1987 ◽

pp. 2347-2357 ◽

Cited By ~ 6

Author(s):

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Rocco I. Papasergio ◽

Colin L. Raston ◽

Paul Twiss ◽

...

Keyword(s):

Crystal Structures ◽

X Ray ◽

Group 4 ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 4. Synthesis and X-ray crystal structure of the tungsten(V) metallabicyclic complex [{W[(2-CH2C6H4)2]2O}2Mg(C4H8O)4]·CH2Cl2

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9860000789 ◽

1986 ◽

pp. 789-793 ◽

Cited By ~ 15

Author(s):

Lutz M. Engelhardt ◽

Rocco I. Papasergio ◽

Colin L. Raston ◽

Geoffrey Salem ◽

Allan H. White

Keyword(s):

Crystal Structure ◽

X Ray ◽

Axially Asymmetric ◽

Metal Alkyls

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