ChemInform Abstract: Axially Asymmetric Metal Alkyls. Part 5. Synthesis and Reduction to Zr(III) Species of Group 4 Metallepines (ML(η-C5H5)2) (L: (2-CHRC6H4)2- 2; R: H; M: Ti, Zr, or Hf), Isomers of (ZrL(η-C5H5)2) (R: SiMe3), and meso-(M(1,8-(CHSiMe3)2C1

The single-crystal X-ray structural characterization of λ-(R,R)-and δ- (S,S)-[ ZrL (η-C5H5)2], L = [2-CH(SiMe3)C6H4]22-, is recorded for comparison with the λ-(R,S)-/δ-(S,R)-isomer, previously reported.

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ChemInform Abstract: Axially Asymmetric Metal Alkyls. Part 3. Chemical, Electrochemical, and Structural Studies of Group 5A d0,1,2Metallepines.

Chemischer Informationsdienst ◽

10.1002/chin.198601259 ◽

1986 ◽

Vol 17 (1) ◽

Author(s):

S. I. BAILEY ◽

L. M. ENGELHARDT ◽

W.-P. LEUNG ◽

C. L. RASTON ◽

I. M. RITCHIE ◽

...

Keyword(s):

Structural Studies ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 1. Lithium alkyls of 2,2′-dimethylbiphenyl and its trimethylsilylmethylated compounds: crystal structures of [{Li(Me2NCH2CH2NMe2)}2{(2-CHRC6H4)2}] for R = H (polymeric) and R = SiMe3(monomeric)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9840000321 ◽

1984 ◽

pp. 321-330 ◽

Cited By ~ 17

Author(s):

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Colin L. Raston ◽

Paul Twiss ◽

Allan H. White

Keyword(s):

Crystal Structures ◽

Axially Asymmetric ◽

Metal Alkyls

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ChemInform Abstract: AXIALLY ASYMMETRIC METAL ALKYLS. PART 1. LITHIUM ALKYLS OF 2,2′-DIMETHYLBIPHENYL AND ITS TRIMETHYLSILYLMETHYLATED COMPOUNDS: CRYSTAL STRUCTURES OF α,α′-BIS((N,N,N′,N′-TETRAMETHYLETHYLENEDIAMINE)LITHIO)-2,2′-DIMETHY# LBIPHENYL AND -2,2

Chemischer Informationsdienst ◽

10.1002/chin.198423264 ◽

1984 ◽

Vol 15 (23) ◽

Author(s):

L. M. ENGELHARDT ◽

W.-P. LEUNG ◽

C. L. RASTON ◽

P. TWISS ◽

A. H. WHITE

Keyword(s):

Crystal Structures ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 2. Synthesis of the di-Grignard reagent [{Mg(thf)nCl}2R][thf = tetrahydrofuran, R =(2-CH2C6H4)22–] and 6,7-dihydro-5H-dibenzo[c,e]-silepines and -stannepines; X-ray crystal structures of [SnPh2R] and δ-SS- and λ-RR-[SnPh2{[2-CH(SiMe3)C6H4]2}]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9840000331 ◽

1984 ◽

pp. 331-340 ◽

Cited By ~ 9

Author(s):

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Colin L. Raston ◽

Paul Twiss ◽

Allan H. White

Keyword(s):

Crystal Structures ◽

Grignard Reagent ◽

X Ray ◽

Axially Asymmetric ◽

Metal Alkyls

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Axially asymmetric metal alkyls. Part 3. Chemical, electrochemical, and structural studies of Group 5A d0,1,2metallepines [M{(2-CH2C6H4)2}(η-C5H5)2]z(M = Nb or Ta; z=1–, 0, or 1+); synthesis of [Nb{2-CH2(C6H4)2Me-2′}X(η-C5H5)2](X = Cl or CO) and [{(η-C5H5)2ClV}2{(2-CH2C6H4)2}], and electrochemistry of [M(CH2Ph)2 –nCln(η-C5H5)2](n= 0, M = Nb, or Ta; n= 1, M = V)

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9850001747 ◽

1985 ◽

pp. 1747-1759 ◽

Cited By ~ 8

Author(s):

Stuart I. Bailey ◽

Lutz M. Engelhardt ◽

Wing-Por Leung ◽

Colin L. Raston ◽

Ian M. Ritchie ◽

...

Keyword(s):

Structural Studies ◽

Axially Asymmetric ◽

Metal Alkyls

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Neutral and zwitterionic group 4 metal alkyls with ancillary boroxide ligands

Dalton Transactions ◽

10.1039/b414155e ◽

2004 ◽

pp. 3428 ◽

Cited By ~ 10

Author(s):

Sarah C. Cole ◽

Martyn P. Coles ◽

Peter B. Hitchcock

Keyword(s):

Group 4 ◽

Group 4 Metal ◽

Metal Alkyls

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