ChemInform Abstract: Synthesis, Characterization, and Reactivity of Iron Carbonyl Clusters Containing Bismuth or Antimony. Crystal Structures of Isomorphous (Et4N) (BiFe3Cr(CO)17) and (Et4N) (SbFe3Cr(CO)17) and the Ring Complex Bi2Fe2(CO)8Me2.

10.1002/chin.198945263 ◽

1989 ◽

Vol 20 (45) ◽

Author(s):

K. H. WHITMIRE ◽

M. SHIEH ◽

J. CASSIDY

Keyword(s):

Crystal Structures ◽

Iron Carbonyl ◽

Carbonyl Clusters ◽

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Synthesis, characterization, and reactivity of iron carbonyl clusters containing bismuth or antimony. Crystal structures of isomorphous [Et4N][BiFe3Cr(CO)17] and [Et4N][SbFe3Cr(CO)17] and the ring complex Bi2Fe2(CO)8Me2

Inorganic Chemistry ◽

10.1021/ic00315a018 ◽

1989 ◽

Vol 28 (16) ◽

pp. 3164-3170 ◽

Author(s):

Kenton H. Whitmire ◽

Minghuey Shieh ◽

Juanita Cassidy

Keyword(s):

Crystal Structures ◽

Iron Carbonyl ◽

Carbonyl Clusters ◽

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Radical Processes in the Reduction of Nitrobenzene Promoted by Iron Carbonyl Clusters. X-ray Crystal Structures of [Fe3(CO)9(.mu.3-NPh)]2-, [HFe3(CO)9(.mu.3-NPh)]-, and the Radical Anion [Fe3(CO)11]-.bul.

Organometallics ◽

10.1021/om00001a054 ◽

1995 ◽

Vol 14 (1) ◽

pp. 387-400 ◽

Author(s):

Fabio Ragaini ◽

Jeong-Sup Song ◽

David L. Ramage ◽

Gregory L. Geoffroy ◽

Glenn A. P. Yap ◽

...

Keyword(s):

Crystal Structures ◽

Radical Anion ◽

Iron Carbonyl ◽

Carbonyl Clusters ◽

X Ray ◽

Radical Processes

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Synthesis of iron carbonyl clusters with trigonal-bipyramidal E2Fe3 cores (E = Ge, Si). Crystal structures of (.mu.3-GeEt)2Fe3(CO)9, [.mu.3-Ge{Fe(CO)2Cp}]2Fe3(CO)9, and [.mu.3-Si{Fe(CO)2Cp}]2Fe3(CO)9

Organometallics ◽

10.1021/om00159a010 ◽

1990 ◽

Vol 9 (9) ◽

pp. 2436-2442 ◽

Author(s):

Skelte G. Anema ◽

Kenneth M. Mackay ◽

Brian K. Nicholson ◽

Martin Van Tiel

Keyword(s):

Crystal Structures ◽

Iron Carbonyl ◽

Carbonyl Clusters ◽

Trigonal Bipyramidal

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Facile Syntheses and Transformations of a Series of Tellurium-Iron Carbonyl Clusters: Crystal Structures of [PhCH2NMe3]2[Te6Fe8(CO)24], Fe2(CO)6(.mu.-TeCHCl2)2, and Fe2(CO)6(.mu.-TeCHPhTe)

Inorganic Chemistry ◽

10.1021/ic00112a043 ◽

1995 ◽

Vol 34 (8) ◽

pp. 2251-2254 ◽

Author(s):

Minghuey Shieh ◽

Pao-Fei Chen ◽

Yi-Chou Tsai ◽

Mei-Huey Shieh ◽

Shie-Ming Peng ◽

...

Keyword(s):

Crystal Structures ◽

Iron Carbonyl ◽

Carbonyl Clusters

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Synthesis, Characterisation, Crystal Structures, Reactivity, and Electrochemistry of Ruthenium-Nitrido, Ruthenium-Cobalt-Imido and Ruthenapyrrolidone Carbonyl Clusters Containing Alkyne Ligands

Chemistry - A European Journal ◽

10.1002/1521-3765(20010105)7:1<258::aid-chem258>3.0.co;2-i ◽

2001 ◽

Vol 7 (1) ◽

pp. 258-271 ◽

Author(s):

Emmie Ngai-Man Ho ◽

Zhenyang Lin ◽

Wing-Tak Wong

Keyword(s):

Crystal Structures ◽

Carbonyl Clusters

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Supported ammonia synthesis catalysts based on potassium derivatives of anionic ruthenium, osmium and iron carbonyl clusters. The first catalysts on carbon support exhibiting activity in ammonia synthesis in the absence of a specially added electron promoter

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(98)00198-8 ◽

1999 ◽

Vol 139 (2-3) ◽

pp. 219-225 ◽

Author(s):

S Yunusov

Keyword(s):

Ammonia Synthesis ◽

Carbon Support ◽

Iron Carbonyl ◽

Carbonyl Clusters ◽

Synthesis Catalysts ◽

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Synthesis and reactivity of iron carbonyl clusters containing alkynethiolate ligands

Inorganica Chimica Acta ◽

10.1016/j.ica.2004.09.011 ◽

2005 ◽

Vol 358 (5) ◽

pp. 1521-1530 ◽

Author(s):

Alberto Cabrera ◽

Esther Delgado ◽

Cesar Pastor ◽

Miguel A. Maestro ◽

Félix Zamora

Keyword(s):

Iron Carbonyl ◽

Carbonyl Clusters

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Five dinuclear iron carbonyl complexes based on substituted tetramethylcyclopentadienyl ligands: synthesis and crystal structures

Journal of Coordination Chemistry ◽

10.1080/00958972.2013.873533 ◽

2014 ◽

Vol 67 (1) ◽

pp. 64-71 ◽

Author(s):

Zhihong Ma ◽

Kaiming Guo ◽

Na Wang ◽

Hong Wang ◽

Zhangang Han ◽

...

Keyword(s):

Crystal Structures ◽

Iron Carbonyl ◽

Carbonyl Complexes ◽

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Synthesis, characterization and crystal structures of a series of ruthenium µ4-nitrene carbonyl clusters

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9960001707 ◽

1996 ◽

pp. 1707-1720 ◽

Author(s):

Kenneth Ka Hong Lee ◽

Wing Tak Wong

Keyword(s):

Crystal Structures ◽

Carbonyl Clusters

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Ruthenium and Iron Carbonyl Clusters Catalyzed Reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl)benzamide

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.396-398.2485 ◽

2011 ◽

Vol 396-398 ◽

pp. 2485-2488

Author(s):

Bao Hua Zhu ◽

Guo Hua Xu ◽

Zhi Wei Xia

Keyword(s):

Ir Spectroscopy ◽

Elemental Analysis ◽

Iron Carbonyl ◽

Carbonyl Cluster ◽

Carbonyl Clusters ◽

Excellent Yield ◽

Ruthenium Carbonyl ◽

Vis Spectroscopy

One new Ruthenium and one known Iron bimetallic carbonyl clusters containing triphos (1,1,1-tris(diphenylphosphinomethyl)ethane) ligand have been prepared as catalyst to study the reduction of amide to amine. All clusters were characterized by elemental analysis, 1HNMR, 31PNMR and IR spectroscopy. The reduction of N,N-dimethylbenzamide and N,N-diethyl-(3-methyl) benzamide catalyzed by Ru and Fe carbonyl clusters were investigated at 100 ~ 110 °C for 24 ~ 28h, polymethylhydrogensiloxane (PMHS) as reduction agent. The products were analysized using GC-MS, IR and UV-vis spectroscopy and an excellent yield (97%) of N,N-diethyl- (3-methyl)benzamine was obtained when using 3 mol% of bimetallic ruthenium carbonyl cluster as catalyst. The data of IR and UV-vis show that the frameworks of clusters are not changed remarkably during the reaction.

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