Thermal Stability of Potassium-Promoted Cobalt Molybdenum Nitride Catalysts for Ammonia Synthesis

The application of cobalt molybdenum nitrides as ammonia synthesis catalysts requires further development of the optimal promoter system, which enhances not only the activity but also the stability of the catalysts. To do so, elucidating the influence of the addition of alkali metals on the structural properties of the catalysts is essential. In this study, potassium-promoted cobalt molybdenum nitrides were synthesized by impregnation of the precursor CoMoO4·3/4H2O with aqueous KNO3 solution followed by ammonolysis. The catalysts were characterized with the use of XRD and BET methods, under two conditions: as obtained and after the thermal stability test. The catalytic activity in the synthesis of ammonia was examined at 450 °C, under 10 MPa. The thermal stability test was carried out by heating at 650 °C in the same apparatus. As a result of ammonolysis, mixtures of two phases: Co3Mo3N and Co2Mo3N were obtained. The phase concentrations were affected by potassium admixture. The catalytical activity increased for the most active catalyst by approximately 50% compared to non-promoted cobalt molybdenum nitrides. The thermal stability test resulted in a loss of activity, on average, of 30%. Deactivation was caused by the collapse of the porous structure, which is attributed to the conversion of the Co2Mo3N phase to the Co3Mo3N phase.

Boosting Electrochemical Nitrogen Reduction to Ammonia with High Efficiency using LiNb3O8 Electrocatalyst in Neutral Media

Nitrogen reduction reaction (NRR) has great research prospects as a method to replace the industrial Haber-Bosch process for ammonia synthesis. Nevertheless, the efficiency of NRR is mainly depended on the...

Electrochemically promoted ammonia synthesis on an Fe/BaZr0.8Y0.2O3-δ catalyst at ambient pressure

Electrochemically promoted nitrogen reduction on solid-state electrolytes is a promising approach for synthesising ammonia (NH3) under mild conditions. In this study, yttrium-doped barium zirconate (BZY) was chosen as a solid-state...

Green ammonia synthesis using CeO2/RuO2 nanolayers on vertical graphene catalyst via electrochemical route in alkaline electrolyte

The electrochemical synthesis of ammonia at ambient temperature and pressure has a potential to replace conventional ammonia production process. However, low ammonia yield and poor long-term stability of the catalyst...

ALGORITHMIC SUPPORT FOR DECISION-MAKING ON THE EFFICIENCY OF OPERATION OF ABSORPTION AND REFRIGERATION PLANTS OF AMMONIA PRODUCTION

The features of the hardware and technological design of the AM-1360 series ammonia synthesis units operating in Ukraine are established, the main of which is the use of heat-using ammonia-water absorption and refrigeration units in the secondary condensation complex. The analysis of the functioning of the absorption and refrigeration units has been carried out. A significant dependence of their efficiency on external disturbances, such as temperature and humidity of atmospheric air, has been established. This causes significant fluctuations in the cooling temperature of the circulating gas in the evaporators of absorption-refrigeration units, which significantly affects the efficiency of ammonia production in general. Based on the results of the analysis of the existing information system, implemented on the basis of the TDC-3000 microprocessor complex, recommendations for its improvement were developed, the presence of which makes it possible to abandon daily analyzes and carry out only control ones to check measuring instruments. Algorithmic support has been developed, implemented in the MATLAB package and tested according to the data of industrial operation of absorption and refrigeration units of the ammonia synthesis unit. This allows the operator, in real production conditions, to obtain operational information on the numerical indicators of the efficiency of operation of absorption and refrigeration units, which characterize their operation to the greatest extent (circulation rate, cooling capacity, circulating gas cooling temperature and thermal coefficient) and make a decision on the possibility of reducing the cooling temperature. of circulation gas in evaporators by changing the frequency of circulation of solutions The created algorithmic software in the MATLAB environment allows embedding a client module, the so-called OPC client. The latter provides technology for free programming of access to current data.