ChemInform Abstract: Thermally and Photochemically Initiated Radical Chain Decomposition of Ketone-Free Methyl(trifluoromethyl)dioxirane.

ChemInform ◽  
2010 ◽  
Vol 23 (1) ◽  
pp. no-no
Author(s):  
W. ADAM ◽  
R. CURCI ◽  
M. E. GONZALEZ NUNEZ ◽  
R. MELLO
Keyword(s):  
Radical Chain ◽  
Chain Decomposition

Catalysis by hydrogen halides in the gas phase. XVIII. Methyl formate and hydrogen bromide

1968 ◽  
Vol 21 (7) ◽  
pp. 1711
Author(s):  
DA Kairaitis ◽  
VR Stimson
Keyword(s):  
Carbon Monoxide ◽  
Gas Phase ◽  
Decomposition Product ◽  
Methyl Formate ◽  
Arrhenius Equation ◽  
Hydrogen Bromide ◽  
Radical Chain ◽  
Hydrogen Halides ◽  
Chain Decomposition ◽  
First Order

Hydrogen bromide catalyses the decomposition of methyl formate into carbon monoxide and methanol at 390-460�. The radical chain decomposition product, methane, is formed in only a small amount that is further reduced by the addition of inhibitor. The reaction is homogeneous and molecular, is first order in each reactant, and follows the Arrhenius equation: k2 = 1012.50exp(-32200/RT)sec-1 ml mole-1 It is not reversed by added methanol.

Benzoyl Hypoiodite and the Radical-Chain Decomposition of Phenyliodine Dibenzoate1

1966 ◽  
Vol 31 (4) ◽  
pp. 1153-1159 ◽  
Author(s):  
J. E. Leffler ◽  
W. J. M. Mitchell ◽  
B. C. Menon
Keyword(s):  
Radical Chain ◽  
Chain Decomposition
Sign in / Sign up

Export Citation Format

Share Document