A Highly Regio- and Stereoselective Transition Metal-Catalyzed Hydrosilylation of Terminal Alkynes under Ambient Conditions of Air, Water, and Room Temperature.

ChemInform ◽  
2003 ◽  
Vol 34 (43) ◽  
Author(s):  
Wei Wu ◽  
Chao-Jun Li
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Terminal Alkynes ◽  
Ambient Conditions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition Metal Catalyzed Hydrosilylation and Hydroboration of Terminal Alkynes in Ionic Liquids

ChemInform ◽  
2003 ◽  
Vol 34 (2) ◽  
Author(s):  
S. Aubin ◽  
F. Le Floch ◽  
D. Carrie ◽  
J. P. Guegan ◽  
M. Vaultier
Keyword(s):  
Ionic Liquids ◽  
Transition Metal ◽  
Terminal Alkynes ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Ruthenium-Catalyzed Room-Temperature Coupling of α-Keto Sulfoxonium Ylides and Cyclopropanols for δ-Diketone Synthesis

2021 ◽  
Author(s):  
Lili Fang ◽  
Shuaixin Fan ◽  
Tielei Li ◽  
Weiping Wu ◽  
Jin Zhu
Keyword(s):  
Transition Metal ◽  
Room Temperature ◽  
Low Cost ◽  
Rhodium Catalyst ◽  
Catalytic Method ◽  
Reaction Conditions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Previous transition metal-catalyzed synthesis of δ-diketones is plagued by high cost of rhodium catalyst and harsh reaction conditions. Herein a low-cost, room temperature ruthenium catalytic method is developed based on...

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