ChemInform Abstract: Direct Method for Carbon-Carbon Bond Formation: The Functional Group Tolerant Cobalt-Catalyzed Alkylation of Aryl Halides.

ChemInform ◽  
2010 ◽  
Vol 41 (39) ◽  
pp. no-no
Author(s):  
Muriel Amatore ◽  
Corinne Gosmini
Keyword(s):  
Functional Group ◽  
Direct Method ◽  
Bond Formation ◽  
Aryl Halides ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Modern Organic Synthesis in the Laboratory

2008 ◽  
Author(s):  
Jie Jack Li ◽  
Chris Limberakis ◽  
Derek A. Pflum
Keyword(s):  
Organic Chemistry ◽  
Graduate Students ◽  
Organic Synthesis ◽  
Functional Group ◽  
Bond Formation ◽  
Reaction Conditions ◽  
Carbon Bond ◽  
Oxidation Reduction ◽  
Carbon Carbon Bond ◽  
Daunting Task

Searching for reaction in organic synthesis has been made much easier in the current age of computer databases. However, the dilemma now is which procedure one selects among the ocean of choices. Especially for novices in the laboratory, it becomes a daunting task to decide what reaction conditions to experiment with first in order to have the best chance of success. This collection intends to serve as an "older and wiser lab-mate" one could have by compiling many of the most commonly used experimental procedures in organic synthesis. With chapters that cover such topics as functional group manipulations, oxidation, reduction, and carbon-carbon bond formation, Modern Organic Synthesis in the Laboratory will be useful for both graduate students and professors in organic chemistry and medicinal chemists in the pharmaceutical and agrochemical industries.

Palladium chloride catalyzed photochemical Heck reaction

2013 ◽  
Vol 91 (5) ◽  
pp. 348-351 ◽  
Author(s):  
Suresh B. Waghmode ◽  
Sudhir S. Arbuj ◽  
Bina N. Wani ◽  
C.S. Gopinath
Keyword(s):  
Visible Light ◽  
Heck Reaction ◽  
Palladium Nanoparticles ◽  
Bond Formation ◽  
Aryl Halides ◽  
Palladium Chloride ◽  
Carbon Bond ◽  
Excellent Yield ◽  
Carbon Carbon Bond ◽  
Uv Visible

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

Heck-Type Cyclization of Oxime Ethers: Stereoselective Carbon—Carbon Bond Formation with Aryl Halides to Produce Heterocyclic Oximes.

ChemInform ◽  
2007 ◽  
Vol 38 (51) ◽  
Author(s):  
Hiroaki Ohno ◽  
Akimasa Aso ◽  
Yoichi Kadoh ◽  
Nobutaka Fujii ◽  
Tetsuaki Tanaka
Keyword(s):  
Bond Formation ◽  
Aryl Halides ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Heck-Type Cyclization of Oxime Ethers: Stereoselective Carbon–Carbon Bond Formation with Aryl Halides To Produce Heterocyclic Oximes

2007 ◽  
Vol 119 (33) ◽  
pp. 6441-6444 ◽  
Author(s):  
Hiroaki Ohno ◽  
Akimasa Aso ◽  
Yoichi Kadoh ◽  
Nobutaka Fujii ◽  
Tetsuaki Tanaka
Keyword(s):  
Bond Formation ◽  
Aryl Halides ◽  
Carbon Bond ◽  
Carbon Carbon Bond
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