ChemInform Abstract: Rapid and Slow Generation of 1-Trifluoromethylvinyllithium: Syntheses and Applications of CF3-Containing Allylic Alcohols, Allylic Amines, and Vinyl Ketones.

ChemInform ◽  
2010 ◽  
Vol 41 (52) ◽  
pp. no-no
Author(s):  
Ryo Nadano ◽  
Kohei Fuchibe ◽  
Masahiro Ikeda ◽  
Hiroki Takahashi ◽  
Junji Ichikawa
Keyword(s):  
Allylic Alcohols ◽  
Allylic Amines

Iridium-Catalyzed Synthesis of Primary Allylic Amines from Allylic Alcohols: Sulfamic Acid as Ammonia Equivalent

2007 ◽  
Vol 46 (17) ◽  
pp. 3139-3143 ◽  
Author(s):  
Christian Defieber ◽  
Martin A. Ariger ◽  
Patricia Moriel ◽  
Erick M. Carreira
Keyword(s):  
Sulfamic Acid ◽  
Allylic Alcohols ◽  
Allylic Amines

Enantiomerically Enriched Allylic Alcohols and Allylic Amines via C–C Bond-Forming Hydrogenation: Asymmetric Carbonyl and Imine Vinylation

2007 ◽  
Vol 40 (12) ◽  
pp. 1394-1401 ◽  
Author(s):  
Eduardas Skucas ◽  
Ming-Yu Ngai ◽  
Venukrishnan Komanduri ◽  
Michael J. Krische
Keyword(s):  
Allylic Alcohols ◽  
Allylic Amines ◽  
Bond Forming

scholarly journals Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes

2010 ◽  
Vol 82 (7) ◽  
pp. 1461-1469 ◽  
Author(s):  
Luca Mantilli ◽  
David Gérard ◽  
Sonya Torche ◽  
Céline Besnard ◽  
Clément Mazet
Keyword(s):  
Asymmetric Catalysis ◽  
Organic Synthesis ◽  
Industrial Application ◽  
Allylic Alcohols ◽  
Iridium Complexes ◽  
Allylic Amines ◽  
Reaction Conditions ◽  
Significant Challenge ◽  
Catalytic Asymmetric

The catalytic asymmetric isomerization of allylic amines to enamines stands out as one of the most accomplished and well-studied reactions in asymmetric catalysis as illustrated by its industrial application. In contrast, the related asymmetric isomerization of primary allylic alcohols to the corresponding aldehydes still constitutes a significant challenge in organic synthesis. Herein, we show that under appropriate reaction conditions, iridium-hydride catalysts promote the isomerization of primary allylic alcohols under very mild reaction conditions. The best catalysts deliver the desired chiral aldehydes with unprecedented levels of enantioselectivity and good yields. Mechanistic hypotheses have been drawn based on preliminary investigations.

ChemInform Abstract: Synthesis of Cinnamyl Amines from the Baylis-Hillman Adducts: Transformation of Allylic Alcohols to Allylic Amines.

ChemInform ◽  
2001 ◽  
Vol 32 (12) ◽  
pp. no-no
Author(s):  
Hong Jung Lee ◽  
Yun Mi Chung ◽  
Ka Young Lee ◽  
Jae Nyoung Kim
Keyword(s):  
Allylic Alcohols ◽  
Allylic Amines

Catalytic Asymmetric Rearrangement of AllylicN-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines

2003 ◽  
Vol 5 (11) ◽  
pp. 1809-1812 ◽  
Author(s):  
Larry E. Overman ◽  
Carolyn E. Owen ◽  
Mary M. Pavan ◽  
Christopher J. Richards
Keyword(s):  
Allylic Alcohols ◽  
Allylic Amines ◽  
Catalytic Asymmetric
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