ChemInform Abstract: Bent Bonds and the Antiperiplanar Hypothesis as a Simple Model to Predict Diels-Alder Reactivity: Retrospective or Perspective?

ChemInform ◽  
2013 ◽  
Vol 44 (41) ◽  
pp. no-no
Author(s):  
Ghislain Deslongchamps ◽  
Pierre Deslongchamps
Keyword(s):  
Simple Model ◽  
Diels Alder ◽  
Bent Bonds

Chemistry of bent bonds. XXX. Diels-Alder approach to inside-outside bicyclics

1972 ◽  
Vol 94 (20) ◽  
pp. 7183-7184 ◽  
Author(s):  
Paul G. Gassman ◽  
Randolph P. Thummel
Keyword(s):  
Diels Alder ◽  
Bent Bonds

Bent bonds and the antiperiplanar hypothesis – a simple model to rationalize [1,3]-sigmatropic alkyl shifts

2016 ◽  
Vol 14 (32) ◽  
pp. 7754-7767 ◽  
Author(s):  
Ghislain Deslongchamps ◽  
Pierre Deslongchamps
Keyword(s):  
Simple Model ◽  
Sigmatropic Rearrangements ◽  
Bent Bonds

The stereochemical outcome of [1,3]-sigmatropic rearrangements can be rationalized by the use of olefinic tau (τ) bonds, and by considering that diradical intermediates have pyramidal character.

Chemistry of bent bonds. XLIII. Cycloadditions to cyclic 1,3-dienes. Diels-Alder route to inside-outside bicyclics

1974 ◽  
Vol 96 (22) ◽  
pp. 6948-6955 ◽  
Author(s):  
Paul G. Gassman ◽  
Stewart R. Korn ◽  
Randolph P. Thummel
Keyword(s):  
Diels Alder ◽  
Bent Bonds

Chaos and secular cycles in a structurally simple model society

2012 ◽  
Author(s):  
Alexander Medvinsky ◽  
Alexey Rusakov
Keyword(s):  
Simple Model

A Simple Model of Changes in Lumbar Intervertebral Angles During Sagittal Torso Flexion

2011 ◽  
Author(s):  
Riley E. Splittstoesser ◽  
Greg G. Knapik ◽  
William S. Marras
Keyword(s):  
Simple Model
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