The synthesis and crystal structure of a trinuclear molybdenum cluster compound [Mo3(μ-O)(μ-S)3(μ(μ-OAc)2(dtp)2·(Py)]·0.5H2O

2010 ◽  
Vol 10 (6) ◽  
pp. 500-507 ◽  
Author(s):  
Shao-Fang Lu ◽  
Jian-Quan Huang ◽  
Zi-Xiang Huang ◽  
Bin Zhang ◽  
Jin-Ling Huang
1999 ◽  
Vol 54 (3) ◽  
pp. 381-384 ◽  
Author(s):  
Joachim Pethe ◽  
Joachim Strähle

The photolysis of Cr(CO)6 and Ph3PAuN3 (1:2) in thf yields the unstable cluster cation [(Ph3PAu)5Cr(CO)4]+ that slowly decomposes to form the new homometallic gold cluster [Au(AuNCO)(AuPPh3)8]Cl. The cluster compound crystallizes in form of red needles in the tetragonal space group I4 with a = 2214.1(3), c = 1408.9(2) pm, and Z = 2. The inner skeleton of the cluster with the symmetry C4 consists of a centered square antiprism of nine Au atoms with the square faces of the antiprism being bridged by the AuNCO group, and a Cl- anion, respectively. The shortest Au-Au distances exist between the central and the 8+1 peripheral Au atoms ranging between 263.5( 1) and 270.6(3) pm, the four Au-Cl distances are 280(1) pm.


1989 ◽  
Vol 8 (4) ◽  
pp. 920-925 ◽  
Author(s):  
Bart. Fischer ◽  
Henk. Kleijn ◽  
Jaap. Boersma ◽  
Gerard. Van Koten ◽  
Anthony L. Spek

2010 ◽  
Vol 21 (7) ◽  
pp. 1230-1236 ◽  
Author(s):  
Bárbara Tirloni ◽  
Davi F. Back ◽  
Robert A. Burrow ◽  
Gelson N. M. de Oliveira ◽  
Marcos A. Villetti ◽  
...  

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