1,3-Dipolar Cycloaddition Reactions of Organic Azides with Morpholinobuta-1,3-dienes and with anα-Ethynyl-enamine

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Gerhard Maas ◽  
Frank-Gerrit Klärner
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Muriel Compain-Batissou ◽  
Jacques Gentili ◽  
Nadia Walchshofer ◽  
Monique Domard ◽  
Bernard Fenet ◽  
...  

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Sultan T. Abu-Orabi ◽  
M. Adnan Atfah ◽  
Ibrahim Jibril ◽  
Fakhri M. Mari'i ◽  
Amer Al-Sheikh Ali

Heterocycles ◽  
2007 ◽  
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Muriel Compain-Batissou ◽  
Jacques Gentili ◽  
Nadia Walchshofer ◽  
Monique Domard ◽  
...  

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1990 ◽  
Vol 21 (11) ◽  
Author(s):  
S. T. ABU-ORABI ◽  
M. A. ATFAH ◽  
I. JIBRIL ◽  
F. M. MARI'I ◽  
A. A.-S. ALI

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Raju Kumar ◽  
Abdulrahman Almansour ◽  
Subbu Perumal

2002 ◽  
Vol 67 (3) ◽  
pp. 353-364 ◽  
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Petr Melša ◽  
Ctibor Mazal

Diastereoselectivity of 1,3-dipolar cycloaddition reactions of benzyl azide, diazomethane, a nitrile oxide and a nitrile imine to α-methylidene-γ-lactone dipolarophile was effectively controlled by a bulky γ-substituent, 4-methyl-2,6,7-trioxabicyclo[2.2.2]octan-1-yl in γ-position of the dipolarophile. The dipoles added from the less hindered face of the double bond with an excellent selectivity. Enantiomerically pure dipolarophile was prepared from the easily available (S)-5-oxotetrahydrohydrofuran-2-carboxylic acid.


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