Ring-opening polymerization of lactones by mono(cyclopentadienyl)titanium complexes

Macromolecular Symposia ◽

10.1002/masy.19950950117 ◽

1995 ◽

Vol 95 (1) ◽

pp. 195-202 ◽

Author(s):

Jun Okuda ◽

Thomas Kleinhenn ◽

Peter König ◽

Insa Taden ◽

Silvana Ngo ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes

Download Full-text

Titanium complexes containing new dianionic tetradentate [ONNO]-type ligands with benzyl substituents on bridging nitrogen atoms: Syntheses, X-ray structures, and catalytic activities in ring opening polymerization of lactide

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2009.06.037 ◽

2009 ◽

Vol 694 (21) ◽

pp. 3409-3417 ◽

Author(s):

So Han Kim ◽

Junseong Lee ◽

Da Jung Kim ◽

Jung Hee Moon ◽

Sungwoo Yoon ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

X Ray ◽

Catalytic Activities

Download Full-text

Titanium complexes bearing benzotriazole iminophenolate ligands as efficient catalysts for ring-opening polymerization of cyclic esters

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2018.01.018 ◽

2018 ◽

Vol 90 ◽

pp. 1-7 ◽

Author(s):

Dei-Cheng Liu ◽

Chen-Yu Li ◽

Pei-Hua Lin ◽

Jhy-Der Chen ◽

Chen-Yen Tsai ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

Download Full-text

Titanium complexes based on aminodiol ligands for the ring-opening polymerization of ε-caprolactone, rac-β-butyrolactone, and trimethylene carbonate

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.24986 ◽

2011 ◽

Vol 49 (24) ◽

pp. 5176-5185 ◽

Author(s):

Deivasagayam Dakshinamoorthy ◽

Frédéric Peruch

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Trimethylene Carbonate ◽

Titanium Complexes

Download Full-text

Mono(cyclopentadienyl)titanium complexes as initiators for the living ring-opening polymerization of .epsilon.-caprolactone

Macromolecules ◽

10.1021/ma00072a036 ◽

1993 ◽

Vol 26 (20) ◽

pp. 5530-5532 ◽

Author(s):

Jun Okuda ◽

Ilya L. Rushkin

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes

Download Full-text

Catalytic improvement of titanium complexes bearing bis(aminophenolate) in ring-opening polymerization of l -lactide and ɛ-caprolactone

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2014.07.003 ◽

2014 ◽

Vol 394 ◽

pp. 97-104 ◽

Author(s):

Hsiu-Wei Ou ◽

Hsing-Yin Chen ◽

His-Ching Tseng ◽

Mon-Wei Hsiao ◽

Yu-Lun Chang ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes

Download Full-text

Bis(amido)titanium complexes having chelating diaryloxo ligands bridged by sulfur or methylene and their catalytic behaviors for ring-opening polymerization of cyclic esters

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2003.10.042 ◽

2004 ◽

Vol 689 (3) ◽

pp. 612-619 ◽

Author(s):

Yoshinori Takashima ◽

Yuushou Nakayama ◽

Toshikazu Hirao ◽

Hajime Yasuda ◽

Akira Harada

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

Download Full-text

Titanium Complexes of Tridentate Aminebiphenolate Ligands Containing Distinct N-Alkyls: Profound N-Substituent Effect on Ring-Opening Polymerization Catalysis

Inorganic Chemistry ◽

10.1021/ic301551v ◽

2013 ◽

Vol 52 (4) ◽

pp. 1780-1786 ◽

Author(s):

Lan-Chang Liang ◽

Sheng-Ta Lin ◽

Chia-Cheng Chien

Keyword(s):

Substituent Effect ◽

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

Polymerization Catalysis

Download Full-text

Factors influencing catalytic behavior of titanium complexes bearing bisphenolate ligands toward ring-opening polymerization of L-lactide and ε-caprolactone

eXPRESS Polymer Letters ◽

10.3144/expresspolymlett.2018.11 ◽

2018 ◽

Vol 12 (2) ◽

pp. 126-135 ◽

Author(s):

M-T. Jiang ◽

S. R. Kosuru ◽

Y. H. Lee ◽

W-Y. Lu ◽

J. K. Vandavasi ◽

...

Keyword(s):

Ring Opening ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

Catalytic Behavior ◽

Factors Influencing

Download Full-text

ε-Caprolactone polymerization using titanium complexes immobilized onto silica based materials functionalized with ionic liquids: insights into steric, electronic and support effects

RSC Advances ◽

10.1039/c6ra01220e ◽

2016 ◽

Vol 6 (24) ◽

pp. 19723-19733 ◽

Author(s):

Paula Cruz ◽

Yolanda Pérez ◽

Isabel del Hierro ◽

Rafael Fernández-Galán ◽

Mariano Fajardo

Keyword(s):

Ionic Liquids ◽

Ring Opening ◽

Heterogeneous Catalysts ◽

Ring Opening Polymerization ◽

Titanium Complexes ◽

Support Effects

Heterogeneous catalysts comprised of titanium immobilized on silica imidazolium-based systems have been synthesized for the ring opening polymerization of ε-caprolactone.

Download Full-text

Use of Titanium Complexes Bearing Diphenolate or Calix[n]arene Ligands in α-Olefin Polymerization and the ROP of Cyclic Esters

Catalysts ◽

10.3390/catal10020210 ◽

2020 ◽

Vol 10 (2) ◽

pp. 210 ◽

Author(s):

Orlando Santoro ◽

Carl Redshaw

Keyword(s):

Ring Opening ◽

Olefin Polymerization ◽

Ring Opening Polymerization ◽

Molecular Structures ◽

Titanium Complexes ◽

Cyclic Esters ◽

Arene Ligands ◽

Catalytic Behaviour

In this review, we discuss the use of titanium complexes bearing either bridged diphenolate or calix[n]arene (n = 4, 6, 8) ligation, in the formation of plastics from α-olefins or via the ring opening polymerization (ROP) of cyclic esters. The syntheses, molecular structures and catalytic behaviour of these systems are discussed, as well as where possible, the properties of the resultant polymers.

Download Full-text