Crystalline TiO2 Nanorod Aggregates: Template-Free Fabrication and Efficient Light Harvesting in Dye-Sensitized Solar Cell Applications

2013 ◽  
Vol 30 (9) ◽  
pp. 754-758 ◽  
Author(s):  
Xiao Li Zhang ◽  
Yang Chen ◽  
Alexander M. Cant ◽  
Fuzhi Huang ◽  
Yi-Bing Cheng ◽  
...  
2015 ◽  
Vol 2015 ◽  
pp. 1-9
Author(s):  
Ju Seong Kim ◽  
Seong Sik Shin ◽  
Hyun Soo Han ◽  
Sun Shin ◽  
Jae Ho Suk ◽  
...  

We report TiO2nanobranches/nanoparticles (NBN) hybrid architectures that can be synthesized by a facile solution phase method. The hybrid architecture simultaneously improves light harvesting and charge collection performances for a dye-sensitized solar cell. First, TiO2nanorods with a trunk length of 2 μm were grown on a fluorine-doped tin oxide (FTO)/glass substrate, and then nanobranches and nanoparticles were deposited on the nanorods’ trunks through a solution method using an aqueous TiCl3solution at 80°C. The relative amount of nanobranches and nanoparticles can be controlled by multiplying the number of TiCl3treatments to maximize the amount of surface area. We found that the resultant TiO2NBN hybrid architecture greatly improves the amount of dye adsorption (five times compared to bare nanorods) due to the enhanced surface area, while maintaining a fast charge collection, leading to a three times higher current density and thus tripling the maximum power conversion efficiency for a dye-sensitized solar cell.


2013 ◽  
Vol 546 ◽  
pp. 326-330 ◽  
Author(s):  
Jeong-Hwa Kim ◽  
Dae-Hwan Kim ◽  
Kang-Pil Kim ◽  
Dong-Hwan Jeon ◽  
Dae-Kue Hwang

Nanoscale ◽  
2013 ◽  
Vol 5 (16) ◽  
pp. 7493 ◽  
Author(s):  
Lijun Yang ◽  
Wallace Woon-Fong Leung ◽  
Jingchuan Wang

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