A Cadmium Coordination Polymer with a (4, 6)-Connected 3D Network: Synthesis, Crystal Structure, and Luminescent Properties

2012 ◽  
Vol 638 (3-4) ◽  
pp. 698-701 ◽  
Author(s):  
Yun Xu ◽  
Yun-Xia Che ◽  
Ji-Min Zheng
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Luminescent Properties ◽  
Network Synthesis ◽  
3D Network ◽  
Cadmium Coordination Polymer

A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and π-π Interactions, f[Zn(phen)2(H2O) {Ag(CN)2g][Ag(CN)2]·MeOH}n (phen=1,10-Phenanthroline)

2013 ◽  
Vol 68 (2) ◽  
pp. 161-167 ◽  
Author(s):  
Muhammad Monim-ul-Mehbooba ◽  
Muhammad Ramzan ◽  
Tobias Rüffe ◽  
Heinrich Lang ◽  
Shafqat Naddem ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography ◽  
3D Network ◽  
Argentophilic Interactions

A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, {[Zn(phen)2(H2O){Ag(CN)2}] [Ag(CN)2]·MeOH}n (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)2] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)2(H2O){Ag(CN)2}]+ cations, [Ag(CN)2]- anions and a methanol molecule. The non-coordinated [Ag(CN)2]- anions are linked to the [Zn(phen)2(H2O){Ag(CN)2}]+ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and π-π interactions to give a 3D network.

scholarly journals Synthesis and crystal structure of a new cadmium coordination polymer with 2-(pyrazol-1-yl)-2-thiazoline (PyTn)

2011 ◽  
Vol 67 (a1) ◽  
pp. C752-C753
Author(s):  
R. Pedrero-Marín ◽  
F. Luna-Giles ◽  
A. Bernalte-García ◽  
F. J. Barros-García ◽  
E. Viñuelas-Zahínos ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Synthesis And Crystal Structure ◽  
Cadmium Coordination Polymer
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