A Zinc(II)-Silver(I) Bimetallic Coordination Polymer Assembled Through Argentophilic and π-π Interactions, f[Zn(phen)2(H2O) {Ag(CN)2g][Ag(CN)2]·MeOH}n (phen=1,10-Phenanthroline)

2013 ◽  
Vol 68 (2) ◽  
pp. 161-167 ◽  
Author(s):  
Muhammad Monim-ul-Mehbooba ◽  
Muhammad Ramzan ◽  
Tobias Rüffe ◽  
Heinrich Lang ◽  
Shafqat Naddem ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography ◽  
3D Network ◽  
Argentophilic Interactions

A cyanido-bridged Zn(II)-Ag(I) bimetallic coordination polymer, {[Zn(phen)2(H2O){Ag(CN)2}] [Ag(CN)2]·MeOH}n (1), was prepared using ZnCl2, 1,10-phenanthroline (phen) and K[Ag(CN)2] and characterized by IR spectroscopy, thermal analysis and X-ray crystallography. The crystal structure of 1 consists of dinuclear [Zn(phen)2(H2O){Ag(CN)2}]+ cations, [Ag(CN)2]- anions and a methanol molecule. The non-coordinated [Ag(CN)2]- anions are linked to the [Zn(phen)2(H2O){Ag(CN)2}]+ complex cations through argentophilic interactions leading to the formation of chains. The chains are connected by hydrogen bonds and π-π interactions to give a 3D network.

Systhesis, Characterization and Spectroscopic Properties of (2E,6E)-2,6-Bis(2,3,4-tri-methoxy-benzylidene)cyclohexanone

2011 ◽  
Vol 396-398 ◽  
pp. 2338-2341
Author(s):  
Xing Chuan Wei ◽  
Zhi Li Liu ◽  
Kun Zhang ◽  
Zhi Yun Du ◽  
Xi Zheng
Keyword(s):  
Crystal Structure ◽  
Acetic Acid ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Spectroscopic Properties ◽  
Spectral Studies ◽  
Double Bonds ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography

In this paper, (2E,6E)-2,6-Bis(2,3,4-tri-methoxy -benzylidene)cyclohexanone (omitted as tmbcho) (1) was obtained by the reaction of acetic acid, tetrahydrofuran, cyclohexanone and 2,3,4-tri-methoxy-benzaldehyde. Three non-classic hydrogen bonds were observed in the compound. X-ray crystallography shows that the crystal structure is stabilized by intermolecular C-H•••π interactions and it contains plenty of conjugated double bonds. The title compound was characterized by UV-vis and fluorescent spectral studies.

scholarly journals Crystal structure of an oxalate-bridged tetranuclear 8-hydroxyquinoline Zn(II) cluster: [Zn4Q6(Ox)]0.5n

2011 ◽  
Vol 76 (4) ◽  
pp. 529-537 ◽  
Author(s):  
Jiajun Wang ◽  
Qiang Wang ◽  
Yanjun Sun ◽  
Yuemei Wang ◽  
Guosheng Zhao ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Ir Spectroscopy ◽  
Elemental Analysis ◽  
Chain Structure ◽  
Stacking Interactions ◽  
Monoclinic System ◽  
X Ray ◽  
X Ray Crystallography ◽  
Polymeric Chains

The chain structure of a tetranuclear zinc(II) cluster [Zn4Q6(Ox)]0.5n ([Zn4 (C9H6NO)6(C2O4)]0.5n) (1) (Q = 8- hydroxyquinoline anion, Ox = oxalate dianion) was determined by X-ray crystallography and characterized by elemental analysis, IR spectroscopy and thermal analysis. It crystallizes in the monoclinic system, space group P21/n (No. 14), with the lattice parameters a = 13.2222(15) ?, b = 11.0566(12) ?, c = 16.2224(18) ?, ? = 92.1770(10)?, V = 2369.9(5) ?3, Z = 4, Mr = 607.23 g mol-1, Dc = 1.702 g cm-3. The tetranuclear zinc(II) clusters form 1D polymeric chains parallel to the b-axis. The ?-? stacking interactions involving aryl rings support the formation of the 1D polymeric structure. The neighboring polymeric chains are connected by C-H???? interactions.

Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-Organic Cd(II) Coordination Polymer Based on Helical Units

2013 ◽  
Vol 68 (2) ◽  
pp. 127-132
Author(s):  
Hai-Hua Li ◽  
Peng Zhang ◽  
Jia-Yi Pu ◽  
Yu-Ying Zhao ◽  
Chong-Zhen Mei
Keyword(s):  
Crystal Structure ◽  
Hydrothermal Synthesis ◽  
Ir Spectroscopy ◽  
Coordination Polymer ◽  
Elemental Analysis ◽  
Metal Organic Framework ◽  
Structure And Properties ◽  
X Ray ◽  
X Ray Crystallography ◽  
Metal Organic

A metal-organic framework based on 4-methylphthalic acid (H2L) and 4,4’-bipyridine (bpy), namely {[Cd(L)(bpy)1:5]·2(H2O)}n (1), has been synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, thermogravimetry, and single-crystal X-ray crystallography. Complex 1 exhibits a 3D coordination network based on layers. Each layer consists of left- or right-handed {Cd-L-Cd-bpy-Cd-L-Cd-bpy}n double helices.Water molecules are also incorporated in the network. Compound 1 shows fluorescence at ca. 360 nm upon excitation at 304 nm.

Synthesis and Crystal Structure of the Hydrogen Bonded Complex of Tri-metatoluidylphosphazenyl Oxide with Bis-metatoluidine Hydrochloride

1977 ◽  
Vol 32 (9) ◽  
pp. 1001-1002 ◽  
Author(s):  
T. Stanley Cameron
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Oxygen Atom ◽  
Title Complex ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Bond Lengths ◽  
Π Interactions ◽  
X Ray Crystallography ◽  
Phosphoryl Oxygen

The title complex was synthesised and its structure determined by x-ray crystallography. The structure contains two hydrogen bonds between the phosphoryl oxygen atom and the two meta-toluidinium ions. The P–N bond lengths are significantly different and the differences, attributed to varying p π-d π interactions along the bonds, confirm earlier observations on tri-para-toluidylphosphazenyl oxide.

Synthesis, IR spectrum, thermal behaviour and crystal structure of a novel one-dimensional cyano-bridged zinc(II)/nickel(II) complex

2005 ◽  
Vol 220 (1) ◽  
Author(s):  
Ahmet Karadag ◽  
Hümeyra Pasaoglu ◽  
Gökhan Kastas ◽  
Orhan Büyükgüngör
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Ir Spectrum ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bimetallic Complex ◽  
One Dimensional ◽  
X Ray

AbstractThe cyano-bridged heteronuclear coordination polymer of zinc(II)/nickel(II) has been prepared by N-(2-hydroxyethyl)-ethylendiamine (hydet-en), alternatively named 2-(2-aminoethylamino)-ethanol and characterised by IR and thermal analysis. In the bimetallic complex, the decomposition of hydet-en ligands is seen to be endothermic whereas that of the cyano ligands is found to be exothermic. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The crystal structure of the zinc(II)-nickel(II) complex consists of a one-dimensional polymeric chain –Zn(hydet-en)

Synthesis and Crystal Structure of the Lead(II) Complex with 5-Hydroxyisophthalic Acid

2013 ◽  
Vol 634-638 ◽  
pp. 451-455
Author(s):  
Yan Yang ◽  
Liu Ting Yan ◽  
Rong Huan Qin ◽  
Wen Gui Duan
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Elemental Analysis ◽  
Three Dimensional ◽  
Single Crystal Diffraction ◽  
Intermolecular Hydrogen Bonds ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
3D Network ◽  
Hydrothermal Methods

The lead(II) Complex constructed with 5-hydroxyisophthalic acid, [Pb3(5-hipa)2]n•4H2O(1), (5-hipa = 5-hydro- xyisophthalic acid) has been synthesized by hydrothermal methods and structurally characterized by elemental analysis, IR and X-ray single crystal diffraction. In trinuclear symmetrical complex 1, Pb1 is four-coordinated, Pb2 and Pb3 are three-coordinated by 5-nitroisophthalic acid groups, respectively, which is further connected through intermolecular hydrogen bonds resulting in a three-dimensional (3D) network.

A one-dimensional ZnIIcoordination polymer: poly[dichlorido(μ2-1,4-phenylenediacetato-κ2O:O′)bis{μ2-1,3-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene-κ2N3:N3′}dizinc(II)]

2014 ◽  
Vol 70 (11) ◽  
pp. 1033-1035 ◽  
Author(s):  
Xiao-Juan Xu
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Π Interactions ◽  
Acid Ligand ◽  
Title One ◽  
Methyl Benzene

In the title one-dimensional ZnIIcoordination polymer, [Zn(C10H8O4)0.5Cl(C12H12N6)]n, the asymmetric unit consists of a ZnIIcation, a 1,3-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene ligand and half of a fully deprotonated centrosymmetric 1,4-phenylenediacetic acid ligand. The crystal structure shows a one-dimensional rotaxane-like structure. This coordination polymer is reinforced by C—H...O and C—H...Cl hydrogen bonds and π–π interactions.

New Inclusion Compounds of Selenourea with Tetraethyl- and Tetra-n-propylammonium Halides

1997 ◽  
Vol 53 (2) ◽  
pp. 262-271 ◽  
Author(s):  
Q. Li ◽  
T. C. W. Mak
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Crystal Data ◽  
Tetraethylammonium Chloride ◽  
Space Group ◽  
X Ray ◽  
X Ray Crystallography ◽  
Dimensional Network ◽  
Single Column

Air-sensitive selenourea inclusion complexes tetraethylammonium chloride–selenourea (1/2), (C2H5)4N+.C1−.2[(NH2)2CSe] (1), tetra-n-propyl-ammonium chloride–selenourea (1/3), (n-C3H7)4N+.C1−.3[(NH2)2CSe] (2), tetra-n-propylammonium bromide–selenourea (1/3), (n-C3H7)4N+.Br−.3[(NH2)2CSe] (3), and tetra-n-propylammonium iodide–selenourea (1/1), (n-C3H7)4N+.I−.(NH2)2CSe (4), have been prepared and characterized by X-ray crystallography. Crystal data, Mo Kα radiation: (1), space group P21/n, Z = 4, a = 8.768 (5), b = 11.036 (6), c = 19.79 (1) Å, β = 96.92 (1)°, R F = 0.055 for 1468 observed data; (2), space group Cc, Z = 4, a = 18.091 (4), b = 13.719 (3), c = 11.539 (2) Å, β = 111.93 (3)°, R F = 0.051 for 1187 observed data; (3), space group Cc, Z = 4, a = 18.309  (4), b = 13.807 (3), c = 11.577 (2) Å, β = 112.45 (3)°, R F = 0.049 for 1592 observed data; (4), space group P21/n, Z = 4, a = 8.976 (1), b = 14.455 (2), c = 15.377 (3) Å, β = 94.16(1)°, R F = 0.062 for 1984 observed data. In the crystal structure of (1) the parallel alternate arrangement of selenourea–chloride ribbons and selenourea chains generates a puckered layer and the cations are sandwiched between them. In the isomorphous complexes (2) and (3) wide selenourea–halide double ribbons are crosslinked by bridging selenourea molecules via N—H...Se and N—H...X hydrogen bonds [average N...Se = 3.521 (8) and 3.527 (7), N...Cl = 3.354 (8) and N...Br = 3.500 (7) Å in (2) and (3), respectively] to form a channel-like three-dimensional network and the cations are accommodated in a single column within each channel. In the crystal structure of (4) the selenourea molecules are joined in the shoulder-to-shoulder fashion via N—H...Se hydrogen bonds [N...Se = 3.529 (7) and 3.534 (7) Å] to generate a ribbon and each selenourea molecule also forms a pair of chelating N—H...I hydrogen bonds [N...I = 3.567 (7) and 3.652 (7) Å] to an adjacent iodide ion.

A threefold interpenetrating two-dimensional zinc(II) coordination polymer: synthesis, crystal structure and selective luminescence sensing properties

2019 ◽  
Vol 75 (7) ◽  
pp. 979-984 ◽  
Author(s):  
Chen-Dong Pan ◽  
Jun Wang ◽  
Ju-Qin Xu ◽  
Kang-Feng Zhang ◽  
Xiao-Wan Wang
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Aqueous Solution ◽  
Coordination Polymer ◽  
Diphenyl Ether ◽  
Biological Processes ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Coordination Framework

The Fe3+ ion is the most important element in environmental systems and plays a fundamental role in biological processes. Iron deficiency can result in diseases and highly selective and sensitive detection of trace Fe3+ has become a hot topic. A novel two-dimensional ZnII coordination framework, poly[[μ-4,4′-bis(2-methylimidazol-1-yl)diphenyl ether-κ2 N 3:N 3′](μ-4,4′-sulfonyldibenzoato-κ2 O:O′)zinc(II)], [Zn(C14H8O6S)(C20H18N4O)] n or [Zn(SDBA)(BMIOPE)] n , (I), where H2SDBA is 4,4′-sulfonyldibenzoic acid and BMIOPE is 4,4′-bis(2-methylimidazol-1-yl)diphenyl ether, has been prepared and characterized by IR, elemental analysis, thermal analysis and X-ray diffraction analysis, the latter showing that the coordination polymer exhibits a threefold interpenetrating two-dimensional 44-sql network. In addition, it displays a highly selective and sensitive sensing for Fe3+ ions in aqueous solution.

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