Dynamic and Static Jahn-Teller Effect in Impurities: Determination of the Tunneling Splitting

Author(s):  
Pablo Garcia-Fernandez ◽  
A. Trueba ◽  
M. T. Barriuso ◽  
J. A. Aramburu ◽  
Miguel Moreno
1977 ◽  
Vol 19 (10) ◽  
pp. 381-382
Author(s):  
L. Cianchi ◽  
M. Mancini ◽  
P. Moeetti

1990 ◽  
Vol 45 (5) ◽  
pp. 593-597 ◽  
Author(s):  
Werner Massa ◽  
Roland E. Schmidt

Crystalline Na[MnF4(H2O)2] and Na[MnF4(H2O)2] · H2O have been precipitated from aqueous HF solution of MnO(OH) and NaF. The crystal structure determination of the trihydrate (space group C 2/c, Z = 8, α = 1638.1(2), b = 667.6(2), c = 1130.3(1) pm, β = 103.78(1)°; R/wR = 0.038/0.033 for 1696 independent reflections) showed the presence of isolated octahedral trans-[MnF4(H2O)2]- anions with an elongation of the H2O-Mn—OH2 axis due to the Jahn-Teller effect (Mn 1-O 224.6(2), Mn 1—F(mean) 183.7(1); Mn2-0 218.3(2), Mn2— F(mean) 184.7(2) pm). As a consequence, an unusual H-bond geometry is observed with a tetrahedral (instead of trigonal) environment of the coordinated O atoms. Na[MnF4(H2O)2] is monoclinic (space group C 2/m, C 2 or Cm, a = 816.6(4), b = 677.1(1), c = 496.8(2), β = 114.45(3)°), the crystals show twinning and 1-dimensional disorder.


2019 ◽  
Vol 129 (1) ◽  
pp. 72-80 ◽  
Author(s):  
N. S. Averkiev ◽  
I. B. Bersuker ◽  
V. V. Gudkov ◽  
I. V. Zhevstovskikh ◽  
M. N. Sarychev ◽  
...  

1976 ◽  
Vol 16 (11) ◽  
pp. 340-342 ◽  
Author(s):  
M. Bacci

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