Study of the structure of simple liquids and amorphous solids by statistical geometry methods

1987 ◽  
Vol 28 (3) ◽  
pp. 433-446 ◽  
Author(s):  
N. N. Medvedev ◽  
Yu. I. Naberukhin

In his Bakerian Lecture, Bernal (1964) discussed those ideas of restricted irregularity which are physically realized in random packings of equal hard spheres, with particular reference to the structure of simple liquids. He stressed the need for a science of ‘statistical geometry ’, and took the first steps himself by proposing possible ways of describing such arrays. In this paper, these and other associated ideas are briefly described and extended by deriving an equivalent set of polyhedral subunits essentially inverse to the packing in real space. Examination of two independent high density arrays demonstrates the repro-ducibility of certain metrical and topological properties of these polyhedra, and their correlations over larger elements of volume. As a result, several possible ‘descriptive parameters’ are proposed. Although these essentially ‘numerical’ characteristics facilitate sensitive structural descriptions of any assembly of micro- and macroscopic subunits, we are still unable to characterize an irregular array in formal mathematical terms. Such a formulation of statistical geometry could be a powerful tool for tackling important problems in many branches of science and engineering.



1989 ◽  
Vol 30 (2) ◽  
pp. 253-260 ◽  
Author(s):  
N. N. Medvedev ◽  
V. P. Voloshin ◽  
Yu. I. Naberukhin






1991 ◽  
Vol 73 (4) ◽  
pp. 917-936 ◽  
Author(s):  
Yu. I. Naberukhin ◽  
V.P. Voloshin ◽  
N.N. Medvedev


1990 ◽  
Vol 41 (8) ◽  
pp. 4585-4588 ◽  
Author(s):  
Matthew A. Glaser ◽  
Noel A. Clark


1984 ◽  
Vol 80 (9) ◽  
pp. 4441-4447 ◽  
Author(s):  
S. M. Foiles ◽  
N. W. Ashcroft ◽  
L. Reatto


1973 ◽  
Vol 24 (1) ◽  
pp. 159-187 ◽  
Author(s):  
P A Egelstaff


1970 ◽  
Author(s):  
David Chandler ◽  
John D. Weeks


1988 ◽  
Vol 21 (4) ◽  
pp. L247-L252 ◽  
Author(s):  
N N Medvedev ◽  
V P Voloshin ◽  
Y I Naberukhin


Sign in / Sign up

Export Citation Format

Share Document