Phase equilibria of strong electrolytes in aqueous solutions from total pressure measurements

1981 ◽  
Vol 6 (3-4) ◽  
pp. 149-168 ◽  
Author(s):  
G. Wozny ◽  
H. Cremer
Author(s):  
Andy F. Burcham ◽  
Mark D. Trampe ◽  
Bruce E. Poling ◽  
David B. Manley

1934 ◽  
Vol 6 ◽  
pp. 116-125 ◽  
Author(s):  
J. B. Chloupek ◽  
Vl. Z. Daneš ◽  
B. A. Danešová

1994 ◽  
Vol 39 (3) ◽  
pp. 488-492 ◽  
Author(s):  
Jay A. Hopkins ◽  
Venkat R. Bhethanabotla ◽  
Scott W. Campbell

1999 ◽  
Vol 54 (11) ◽  
pp. 1410-1416 ◽  
Author(s):  
H. Oppermann ◽  
H. Dao Quoc ◽  
A. Morgenstern

The thermodynamical data of solid aluminium lanthanum chloride LaAlCl6 have been obtained by determination of the decomposition equilibria from total pressure measurements. The melting diagram was determined by DTA. The chemical transport of LaCl3 with AlCl3 is suggesting the existence of the gaseous complex LaAl3Cl12. The data are:ΔH(LaAlCl6f,298) =-427,1 ±2,5 kcal/mol, S°(LaAlCl6,f,298) = 61 ±2,5 cal/K-mol,Δ(LaAl3Cl12,g ,298) =-712 ± 7 kcal/mol, S°(LaAl3Cl12,g,298) = 205 ± 3 cal/K-mol.


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