Integrated coal pyrolysis with methane aromatization over Mo/HZSM-5 for improving tar yield

Fuel ◽  
2013 ◽  
Vol 114 ◽  
pp. 187-190 ◽  
Author(s):  
Lijun Jin ◽  
Xun Zhou ◽  
Xinfu He ◽  
Haoquan Hu
2022 ◽  
Vol 2152 (1) ◽  
pp. 012009
Author(s):  
Bo Tian ◽  
Hao Zhang ◽  
Jie Liu ◽  
Yibin Liu ◽  
Chaohe Yang

Abstract With the continuous improvement of big data technology, my country’s coal liquefaction technology has also continued to mature, maintaining a stable industrial development. Traditional coal pyrolysis technology for tar production with the purpose of increasing tar production, such as coal hydropyrolysis, has problems such as high cost of pure hydrogen atmosphere and complex process and equipment operations, which severely restrict its industrial operation process. Based on this, this paper proposes a new technology of coal pyrolysis and depolymerization coupled with oil increase by using hydrogen precipitated by the condensation polymerization reaction at relatively high temperature under big data technology to study the effect of this process on coal pyrolysis for oil production. Experiments show that at 700°C, the tar yield reaches 21.5wt.%, which is 6% and 7% higher than the pyrolysis tar yield under the same conditions under hydrogen and nitrogen atmospheres. At 600°C, the methane aromatization reaction is relatively weak, and it can be seen that the tar yield is only slightly higher than that under hydrogen and nitrogen atmospheres. As the temperature of the methane anaerobic aromatization reaction increases, the equilibrium conversion rate increases accordingly. Therefore, as the reaction temperature increases, the tar yield also begins to increase.


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